Automated optosensor for the determination of carbaryl residues in vegetable edible oils and table olive extracts

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• 作者：A. Ruiz-Medina ; ^{anruiz@ujaen.es} ; E.J. Llorent-Martí ; nez ; M.L. Ferná ; ndez-de Có ; rdova ; P. Ortega-Barrales
• 关键词：Carbaryl ; Pesticide in food ; Automation ; SIA ; MCFIA ; Edible oils ; Olive oil ; Table olives ; QuEChERS ; Maximum pesticide residue limits ; MRL ; Food and regulatory issues ; Food safety ; Food analysis ; Food composition
• 刊名：Journal of Food Composition and Analysis
• 出版年：2012
• 期刊代码：119_08891575
• 类别：abs
• 出版时间：May-June, 2012
• 卷：26
• 期：1-2
• 页码：66-71
• 文件大小：402 K

摘要

Carbaryl, which belongs to the carbamate family, is a broad-spectrum insecticide used to control over 100 species of insects. In this paper, we propose a flow-through optosensor for the determination of this compound in edible vegetable oils (olive, sunflower and corn oils) and table olives. Two automated flow methodologies have been compared in order to develop the proposed system, Sequential Injection Analysis and Multicommutated Flow Injection Analysis, using C₁₈ silica gel as solid support placed in the flow-cell. After proper extraction with a QuEChERS method, the proposed system presents a detection limit of 1 mg kg^鈭?, which is suitable taking into account the maximum residue limits (MRLs) established by Codex Alimentarius in olive oil (25 mg kg^鈭?) and table olives (30 mg kg^鈭?), obtaining relative standard deviations lower than 4%in all cases. Recovery experiments have been carried out in several samples of oils and table olives, at levels equal to and below those established by legislation, ranging between 85 and 115%, therefore demonstrating that the proposed analytical method fulfills the requirements for its applications in quality control analyses.