Editorial

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• 关键词：Nitrosyl linkage isomerism ; Photochemistry ; Matrix photochemistry ; Ruthenium
• 刊名：Pharmacology Biochemistry and Behavior
• 出版年：2008
• 期刊代码：219_00913057
• 类别：med
• 出版时间：August 2008
• 卷：90
• 期：2
• 页码：123-124
• 文件大小：75 K

摘要

Photolysis of [Ru(bipy)₂(NO)Cl](PF₆)₂ and its ¹⁵NO isotopomer in frozen butyl, methylimidazole (bmim) PF₆ glass at ca. 90 K results in appearance of bands characteristic of isonitrosyl and side-on nitrosyl linkage isomers. In addition, weak bands corresponding to free NO in the matrix are also observed. These observations suggest that weakly bound linkage isomers of nitric oxide are likely intermediates in the photolytic release of NO in this and other physiologically relevant NO sources.