Spectroscopic and physicochemical behavior of magnesium phthalocyanine derivatives mono-substituted with a carboxylic acid group
- 作者：Nolwazi Nombona ; Wadzanai Chidawanyika ; Tebello Nyokong ; t.nyokong@ru.ac.za
- 关键词：Magnesium phthalocyanine ; Photodynamic therapy ; Triplet quantum yield ; Singlet oxygen quantum yield
- 刊名：Journal of Molecular Structure
- 出版年：2012
- 期刊代码：62_00222860
- 类别：ch
- 出版时间：28 March, 2012
- 卷：1012
- 期：Complete
- 页码：31-36
- 文件大小：705 K
摘要
This work reports on the synthesis of novel unsymmetrically substituted magnesium phthalocyanine complexes containing one carboxyl group. The physicochemical behavior of these complexes were compared with those of their unmetallated and zinc counterparts. The MgPcs showed interesting absorption spectra with [8,15,22-Tris-(naphtho)-4,5-(3-carboxy-1,2-dioxyphenyl)phthalocyaninato]magnesium (II) showing a large split in the Q band whereas [8,15,22-Tris-(naphtho)-2-(carboxy) phthalocyaninato]magnesium(II) presented only a small splitting. The magnesium phthalocyanine derivatives displayed higher fluorescence quantum yields compared to unmetallated and zinc phthalocyanine counterparts. The latter gave admirable triplet and singlet oxygen quantum yields. These molecules can distinctly be employed in the field of photodynamic therapy in combination with fluorescence imaging.