Memory of chirality in the non-Kolbe reaction of N-arylcarbonylated l-prolines

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• 作者：Matsumura ; Yoshihiro ; Tanaka ; Takayoshi ; Wanyoike ; George Ng'ang'a ; Maki ; Toshihide ; Onomura ; Osamu
• 关键词：Amino acids and derivatives ; Electrochemistry ; Oxidation ; Asymmetric reactions
• 刊名：Journal of Electroanalytical Chemistry
• 出版年：2001
• 期刊代码：27_00220728
• 类别：ph
• 出版时间：July 13, 2001
• 卷：507
• 期：1-2
• 页码：71-74
• 文件大小：95.1 K

摘要

The non-Kolbe reaction of N-arylcarbonylated l-prolines in methanol gave the decarboxylated α-methoxyamine derivatives, which retained the original chirality to some extent, presenting a new memory of chirality in carbenium ion chemistry.