Hemilability and nonrigidity in metal complexes of bidentate P,PS donor ligands

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• 作者：J.W. Faller ; Suzanna C. Milheiro ; Jonathan Parr
• 关键词：Hemilabile ; Fluxional ; Nonrigid
• 刊名：Journal of Organometallic Chemistry
• 出版年：2008
• 期刊代码：64_0022328x
• 类别：ch
• 出版时间：15 April 2008
• 卷：693
• 期：8-9
• 页码：1478-1493
• 文件大小：623 K

摘要

Hemilability and nonrigidity in a series of mixed P,PS donor ligands has been studied in the complexes [Pd(P,PS)Cl₂], [Pd(η³-C₃H₅)(P,PS)][SbF₆], and [Rh(cod)(P,PS)][SbF₆] (P,PS = Ph₂P-Q-P(S)Ph₂). The effect of bite angle, the rigidity of the ligand backbone, and the role of the ancillary ligands are discussed.