Structural forms in complexes of 2,9-dimethyl-1,10-phenanthroline with simple salts of copper(I) and other univalent ‘closed shell’ species
- 作者：Siti Mutrofin ; Eric J. Chan ; Peter C. Healy ; Aless ; ro Marinelli ; Jean Ngoune ; Claudio Pettinari ; Riccardo Pettinari ; Neil Somers ; Brian W. Skelton ; Allan H. White
- 关键词：Copper(I) complexes ; 2 ; 9-Dimethyl-1 ; 10-phenanthroline ; X-ray crystal structure
- 刊名：Inorganica Chimica Acta
- 出版年：2008
- 期刊代码：40_00201693
- 类别：ch
- 出版时间：2 June 2008
- 卷：361
- 期：8
- 页码：2365-2374
- 文件大小：950 K
摘要
Syntheses, spectroscopic and structural characterizations of a series of Cu(I)-phenanthroline complexes are reported. A single crystal X-ray structure determination is recorded for CuNO3:dmp:MeCN (1:1:1), ‘dmp’ = 2,9-dimethyl-1,10-phenanthroline, showing it to be isomorphous with its previously studied tetrafluoroborate, perchlorate and hexafluorophosphate, and silver(I) perchlorate counterparts, the metal atom lying in a trigonal planar [(N
N)Cu(NCMe)] coordination environment, the anion not being coordinated. Structure (re-) determinations are also reported for a number of salts of the [Cu(dmp)2]+ cation: the perchlorate, isomorphous with numerous other salts, not only of copper(I), but also lithium(I)), also the unsolvated nitrate, and a solvated form of the chloride.
N)Cu(NCMe)] coordination environment, the anion not being coordinated. Structure (re-) determinations are also reported for a number of salts of the [Cu(dmp)2]+ cation: the perchlorate, isomorphous with numerous other salts, not only of copper(I), but also lithium(I)), also the unsolvated nitrate, and a solvated form of the chloride.