The 24-h average coarse (
PM10) and fine (PM
2.5) fraction of airborne particulate matter (PM) samples were collected for winter, summer and monsoon seasons during November 2008-April 2009 at an busy roadside in Chennai city, India. Results showed that the 24-h average ambient PM
10 and PM
2.5 concentrations were significantly higher in winter and monsoon seasons than in summer season. The 24-h average PM
10 concentration of weekdays was significantly higher (12-30%) than weekends of winter and monsoon seasons. On weekends, the PM
2.5 concentration was found to slightly higher (4-15%) in monsoon and summer seasons. The chemical composition of PM
10 and PM
2.5 masses showed a high concentration in winter followed by monsoon and summer seasons.
The U.S.EPA-PMF (positive matrix factorization) version 3 was applied to identify the source contribution of ambient PM10 and PM2.5 concentrations at the study area. Results indicated that marine aerosol (40.4%in PM10 and 21.5%in PM2.5) and secondary PM (22.9%in PM10 and 42.1%in PM2.5) were found to be the major source contributors at the study site followed by the motor vehicles (16%in PM10 and 6%in PM2.5), biomass burning (0.7%in PM10 and 14%in PM2.5), tire and brake wear (4.1%in PM10 and 5.4%in PM2.5), soil (3.4%in PM10 and 4.3%in PM2.5) and other sources (12.7%in PM10 and 6.8%in PM2.5).