Infrared emission spectrum of hot D₂O

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• 作者：Nikolai F. Zobov ; Roman I. Ovsannikov ; Sergei V. Shirin ; Oleg L. Polyansky ; Jonathan Tennyson ; Andrew Janka ; Peter F. Bernath
• 关键词：Water vapor ; Line assignments ; Born– ; Oppenheimer approximation
• 刊名：Journal of Molecular Spectroscopy
• 出版年：2006
• 期刊代码：129_00222852
• 类别：ch
• 出版时间：November 2006
• 卷：240
• 期：1
• 页码：112-119
• 文件大小：151 K

摘要

An emission spectrum of hot D₂O (1500 °C) has been analyzed in the 2077–4323 cm⁻¹ region. A considerable number of new vibration-rotation energy levels have been determined and two new vibrational levels identified. The new (0 4 1) and (0 2 2) vibrational levels have estimated band origins of 7343.93 ± 0.01 and 7826.38 ± 0.02 cm⁻¹, respectively.