Water Vapor Line Assignments in the Near Infrared

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• 作者：Polyansky ; Oleg L. ; Zobov ; Nikolai F. ; Viti ; Serena ; Tennyson ; Jonathan
• 刊名：Journal of Molecular Spectroscopy
• 出版年：1998
• 期刊代码：129_00222852
• 类别：ch
• 出版时间：June, 1998
• 卷：189
• 期：2
• 页码：291-300
• 文件大小：528 K

摘要

The high-resolution spectrum of water vapor between 13200 and 16500 cm⁻¹recorded by J.-Y. Mandin, J-P. Chevillard, C. Camy-Peyret, J.-M. Flaud, and J.W. Brault (1986.J. Molec. Spectrosc.,116, 167) is analyzed using high-accuracy linelists obtained using ab initio calculations and spectroscopically determined potential. Assignments to H₂¹⁶O transitions are presented for 663 of the 795 unassigned lines presented in the original paper. In addition, 38 lines are reassigned. The majority of these assignments and reassignments are confirmed by combination differences. These assignments significantly extend the measured data for the 4ν and 4ν + δ polyads and provide the first information on the (240), (033), (160), (170), and (071) bands. It is likely that a significant fraction of the remaining unassigned lines belong to H₂¹⁸O.