Luminescence properties of europium–terbium double activated calcium tungstate phosphor

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• 作者：Nazarov ; M.V. ; Jeon ; D.Y. ; Kang ; J.H. ; Popovici ; E.-J. ; Muresan ; L.-E. ; Zamoryanskaya ; M.V. ; et. al.
• 关键词：78.55. &minus ; m ; 78.60.Hk ; A. Phosphor ; A. CaWO₄ ; Eu ; Tb ; D. Optical properties ; E. Luminescence
• 刊名：Solid State Communications
• 出版年：2004
• 期刊代码：101_00381098
• 类别：ms
• 出版时间：August, 2004
• 卷：131
• 期：5
• 页码：307-311
• 文件大小：233 K

摘要

Double incorporation of Eu³⁺ and Tb³⁺ ions into a CaWO₄ crystalline lattice modifies the luminescence spectrum due to the formation of new emission centers. Depending on the activators concentration and nature, as well as on the interaction between the activators themselves, the luminescence color can be varied within the entire range of the visible spectrum. Variable luminescence was obtained when CaWO₄:Eu,Tb phosphors with 0–5mol%activator ions were exposed to relatively low excitation energies as UV (365 and 254 nm). Under high energy excitation such as VUV (147 nm) radiation or electron beam, white light has been observed.