The oil-gas separation characteristics of ceramic/Teflon AF2400 composite membrane

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• 作者：Yuwang Han^a ; ^{hankeyi@sina.com} ; Fei Ding^a ; Chanxi Hao^b ; Sumin Lv^a ; Xiaoming Wang^a
• 关键词：Ceramic composite membrane ; Teflon AF2400 ; Oil&ndash ; gas separation ; Transformer oil ; Dissolved gas-in-oil analysis
• 刊名：Separation and Purification Technology
• 出版年：2012
• 期刊代码：78_13835866
• 类别：ce
• 出版时间：22 March, 2012
• 卷：88
• 期：Complete
• 页码：19-23
• 文件大小：345 K

摘要

We studied how the transformer oil flow rate affected the permeation characteristics of transformer fault gases in the ceramic/Teflon-AF2400 composite membrane, and we compared the permeation characteristics of the gases in the dissolved state and the gas state. When the oil flow rate increased from 250 to 750 mL/min, the equilibrium time of H₂ and CO reduced by about 40%while that of C2 hydrocarbons had little change, which indicated that the gas diffusion in the oil somewhat affected the oil-gas separation. The C2 hydrocarbons first reached permeation equilibrium in the dissolve state, whereas H₂ first reached permeation equilibrium in the gas state. The FT-IR results indicated that after immersion in the transformer oil, the Teflon AF2400 membrane absorbed some transformer oil that formed a structure similar to supported liquid membrane. The solubility of the gases in the oil determined their permeation characteristics during the transformer oil-gas separation.