MicroRaman, PXRD, EDS and microscopic investigation of magnesium calcite biomineral phases. The case of sea urchin biominerals

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• 作者：B. Borzę ; cka-Prokop ; A. Weseł ; ucha-Birczyń ; ska ; E. Koszowska
• 关键词：Magnesium Calcite ; Biomineral ; MicroRaman ; PXRD ; Sea urchin
• 刊名：Journal of Molecular Structure
• 出版年：2007
• 期刊代码：62_00222860
• 类别：ch
• 出版时间：28 February 2007
• 卷：828
• 期：1-3
• 页码：80-90
• 文件大小：1662 K

摘要

This study concerns Mg-calcite characterization (and in particular molecular structure and microstructural studies of mineral phases) of a sea urchin mineralised test and spines. Sea urchins are spiny sea animals (kingdom Animalia, phylum Echinodermata, class Echinoidea). Microscopic observations, SEM, EDS, PXRD and spectroscopic microRaman methods have been applied to characterize the biomineral parts of the sea urchin. The latter technique is very useful in research of biological systems and especially suitable for monitoring differences within biomineral phases exhibiting varieties of morphological forms. Crystalline magnesium calcium carbonate, Mg_xCa_1−xCO₃ (magnesian calcite; space group R-3cH; a = 4.9594(8) Å, c = 16.886(6) Å), has been identified as the predominant biomineral component.