Mechanistic studies of oxidation of d-arabinose and d-mannose by acidic solution of N-bromoacetamide in presence of chloro-complex of Ru(III) as homogeneous catalyst
- 作者：Ashok Kumar Singh ; Jaya Srivastava ; Shahla Rahmani
- 关键词：Kinetics ; N-Bromoacetamide oxidation ; Arabinose ; Mannose ; Ruthenium(III) chloride catalysis ; Perchloric acid medium
- 刊名：Journal of Molecular Catalysis A ; Chemical
- 出版年：2007
- 期刊代码：57_13811169
- 类别：ch
- 出版时间：18 June 2007
- 卷：271
- 期：1-2
- 页码：151-160
- 文件大小：384 K
摘要
The present paper deals with the kinetics and mechanism of Ru(III)-catalyzed and Hg(II)-co-catalyzed oxidation of d-arabinose(ara) and d-mannose(man) by acidic solution of N-bromoacetamide(NBA). First-order dependence of the reaction on both NBA and sugar at low concentrations shifts to zero-order at their higher concentrations. First-order kinetics with respect to [Ru(III)] throughout its variation was observed in the oxidation of both arabinose and mannose. A positive effect on the oxidation rate is observed for [Hg(II)] and [Cl−] whereas a negative effect is observed for [H+] and [acetamide]. Ionic strength does not influence the oxidation rate. The decrease in the rate of reaction with the increase in dielectric constant (D) of the medium was observed in the oxidation of both reducing sugars and the kinetic data thus obtained were utilized to calculate dAB, the size of activated complex. Various activation parameters have also been calculated. Formic acid and erythronic acid for arabinose and formic acid and arabinonic acid for mannose were identified as main oxidation products of the reactions. Kinetic and equivalence studies together with spectral information, observed effect of dielectric constant on the rate of reaction, activation parameters and multiple regression analysis were made a basis for the formation of a common reaction mechanism for the catalyzed oxidation of both, arabinose and mannose.