Electrochemical properties of dense (La, Sr)MnO_{3 鈭?#xa0;未} films produced by pulsed laser deposition

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• 作者：Pawel Plonczak ; ^{papl@risoe.dtu.dk} ; Daniel Risskov Sø ; rensen ; Martin Sø ; gaard ; Vincenzo Esposito ; Peter Vang Hendriksen
• 关键词：LSM ; Film ; SOFC ; Cathode ; PLD
• 刊名：Solid State Ionics
• 出版年：2012
• 期刊代码：96_01672738
• 类别：ch
• 出版时间：8 June, 2012
• 卷：217
• 期：Complete
• 页码：54-61
• 文件大小：1100 K

摘要

The electrical conductivity and the electrochemical properties of dense La_0.85Sr_0.15MnO_{3 鈭?#xA0;未} (LSM) films, prepared using Pulsed Laser Deposition (PLD) have been investigated. The nano-structure of the LSM films has been characterized using scanning electron microscopy (SEM). The oxygen transport properties of the films were studied using electrochemical impedance spectroscopy (EIS) on symmetrical cells. Electrical conductivity measurement were carried out in an oxygen partial pressure range from 1 to 0.0032 atm, and a temperature range from 950 to 700 掳C. The electrical conductivity at 800 掳C was 116 S cm^鈭?#xA0;1 and did not vary with the p_O2. Impedance spectra were recorded in the temperature range from 600 to 950 掳C in the oxygen partial pressure range from 0.06 to 1.00 atm. At 900 掳C and 1.00 atm the area specific resistance was 30.6 惟 cm² and an activation energy of 2.7 eV was found. The ASR increased with decreasing p_O2. Based on the impedance spectra an oxide ion conductivity of 5.0 脳 10^鈭?#xA0;1 S cm^鈭?#xA0;1 was found at 900 掳C and p_O2 = 1.00 atm. The characteristic length, at which the oxide transport reaction switch from being limited by bulk diffusion to that of surface exchange, was estimated to be approximately 220 and 130 nm at 700 and 900 掳C, respectively.