Sulfonic acid functionalized mesoporous silicas and organosilicas: Synthesis, characterization and catalytic applications

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• 作者：S. Shylesh ; Prinson P. Samuel ; Ch. Srilakshmi ; Renu Parischa ; A.P. Singh
• 关键词：Ethane– ; silica ; Sulfonic acids ; Condensation ; Heterogeneity
• 刊名：Journal of Molecular Catalysis A ; Chemical
• 出版年：2007
• 期刊代码：57_13811169
• 类别：ch
• 出版时间：3 September 2007
• 卷：274
• 期：1-2
• 页码：153-158
• 文件大小：425 K

摘要

Ethane bridged mesoporous organosilicas and MCM-41 having sulfonic acid groups in the pore channels were prepared by co-condensation method as well as grafting method, using 3-mercaptopropyltriethoxysilane (3-MPTS) as the sulfur precursor. TEM and N₂ sorption isotherm analysis revealed that the mesoporous structural ordering is retained after the functionalization and modifications of organic groups while FT-IR, Raman, XPS and solid-state ¹³C CP MAS NMR shows the presence of sulfonic acid groups and the stability of the mesoporous framework. The catalytic activity of the developed materials was evaluated in the liquid phase Claisen–Schmidt condensation reaction of acetophenone with benzaldehyde, to probe the effect of mesoporous support surfaces as well as the role of preparation methods. Results showed that sulfonic acid functionalized ethane–silica samples were more active, selective and stable than the conventional sulfonic acid containing mesoporous catalysts.