Syntheses, characterization and properties of rhenium(I) tricarbonyl complexes based on tetrathiafulvalene substituted naphthyridine ligands

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• 作者：Ya Liao ; Nan Zhou ; Jie Qin ; Yi-Zhi Li ; You-Xuan Zheng ; ^{yxzheng@nju.edu.cn} ; Jing-Lin Zuo ; ^{zuojl@nju.edu.cn}
• 关键词：Tetrathiafulvalenes ; Naphthyridine ligands ; Crystal structures ; Redox chemistry ; Spectroscopic properties
• 刊名：Inorganic Chemistry Communications
• 出版年：2012
• 期刊代码：39_13877003
• 类别：ch
• 出版时间：July, 2012
• 卷：21
• 期：Complete
• 页码：104-108
• 文件大小：789 K

摘要

New amide functional tetrathiafulvalene ligands containing naphthyridine moiety (rong class="boldFont">Lrong>_{rong class="boldFont">1rong>}rong class="boldFont">-Lrong>_{rong class="boldFont">3rong>}) were synthesized. Further coordination reactions of these ligands with Re(CO)₅Cl afford three interesting rhenium tricarbonyl complexes, ClRe(CO)₃(L). Crystal structures of ClRe(CO)₃(rong class="boldFont">Lrong>_{rong class="boldFont">1rong>}) (rong class="boldFont">1rong>) and ClRe(CO)₃(rong class="boldFont">Lrong>_{rong class="boldFont">2rong>}) (rong class="boldFont">2rong>) have been determined. Electrochemical and spectroscopic properties of all compounds are investigated.