Microstructures and microwave dielectric properties of (1 鈭?#xa0;y)La<sub>1鈭?span style='font-style: italic'>xsub>Sm<sub>xsub>(Mg<sub>0.5sub>Sn<sub>0.5sub>)O<sub>3sub>-yCa<sub>0.8sub>Sm<sub>0.4/3sub>TiO<sub>3sub> ceramics
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摘要
The (1 鈭?#xA0;y)La<sub>1鈭?em>xsub>Sm<sub>xsub>(Mg<sub>0.5sub>Sn<sub>0.5sub>)O<sub>3sub>-yCa<sub>0.8sub>Sm<sub>0.4/3sub>TiO<sub>3sub> ceramics were prepared by the conventional solid-state method. The X-ray diffraction patterns of the La<sub>1鈭?em>xsub>Sm<sub>xsub>(Mg<sub>0.5sub>Sn<sub>0.5sub>)O<sub>3sub> ceramics revealed that La<sub>1鈭?em>xsub>Sm<sub>xsub>(Mg<sub>0.5sub>Sn<sub>0.5sub>)O<sub>3sub> is the main crystalline phase, which is accompanied by a little La<sub>2sub>Sn<sub>2sub>O<sub>7sub> as the second phase. An apparent density of 6.59 g/cm<sup>3sup>, a dielectric constant (<sub>rsub>) of 19.9, a quality factor (Q 脳 f) of 70,200 GHz, and a temperature coefficient of resonant frequency (<sub>fsub>) of 鈭?7 ppm/掳C were obtained when the La<sub>0.97sub>Sm<sub>0.03sub>(Mg<sub>0.5sub>Sn<sub>0.5sub>)O<sub>3sub> ceramics were sintered at 1500 掳C for 4 h. The temperature coefficient of resonant frequency (<sub>fsub>) increased from 鈭?7 to +6 ppm/掳C as y increased from 0 to 0.6 when the (1 鈭?#xA0;y)La<sub>0.97sub>Sm<sub>0.03sub>(Mg<sub>0.5sub>Sn<sub>0.5sub>)O<sub>3sub>-yCa<sub>0.8sub>Sm<sub>0.4/3sub>TiO<sub>3sub> ceramics were sintered at 1500 掳C for 4 h. 0.425La<sub>0.97sub>Sm<sub>0.03sub>(Mg<sub>0.5sub>Sn<sub>0.5sub>)O<sub>3sub>-0.575Ca<sub>0.8sub>Sm<sub>0.4/3sub>TiO<sub>3sub> ceramic that was sintered at 1500 掳C for 4 h had a <sub>fsub> of 鈭? ppm/ 掳C.

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