Limiting negative zero-field splitting in tetrakis(imidazole)bis(acetato) nickel(II) complex

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• 作者：Boca ; Roman ; Dlhá ; n ; Lubor ; Haase ; Wolfgang ; Herchel ; Radovan ; Ma&scaron ; lejová ; Anna ; et. al.
• 刊名：Chemical Physics Letters
• 出版年：2003
• 期刊代码：7_00092614
• 类别：ph
• 出版时间：May 20, 2003
• 卷：373
• 期：3-4
• 页码：402-410
• 文件大小：246 K

摘要

Magnetic properties of bis(acetato-O)tetrakis(imidazole-N3)nickel(II) have been investigated by low-temperature magnetic susceptibility as well as high-field magnetisation and subjected to theoretical analysis. A simultaneous fitting of susceptibility and magnetisation gave the following set of magnetic parameters: g_z