Spin crossover in mononuclear and binuclear iron(III) complexes with pentadentate Schiff-base ligands

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• 作者：Boca ; Roman ; Fukuda ; Yutaka ; Gembický ; Milan ; Herchel ; Radovan ; Jaro&scaron ; ciak ; Rastislav ; et. al.
• 刊名：Chemical Physics Letters
• 出版年：2000
• 期刊代码：7_00092614
• 类别：ph
• 出版时间：July 28, 2000
• 卷：325
• 期：4
• 页码：411-419
• 文件大小：195 K

摘要

A series of mononuclear hexacoordinate iron(III) complexes, [Fe(⁵L)(py)]BPh₄, and binuclear hexacoordinate iron(III) complexes, [(⁵L)Fe(μ²-bpy)Fe(⁵L)](BPh₄)₂, has been prepared and their magnetic properties were investigated; the pentadentate ligands were derivatives of ⁵L