TEM and Raman characterisation of diamond micro- and nanostructures in carbon spherules from upper soils
- 作者：Z.Q. Yang ; J. Verbeeck ; D. Schryvers ; N. Tarcea ; J. Popp ; W. Rö ; sler
- 关键词：Diamond nanoparticles ; Diamond microflakes ; Carbon spherules ; Impact
- 刊名：Diamond and Related Materials
- 出版年：2008
- 期刊代码：30_09259635
- 类别：ms
- 出版时间：June 2008
- 卷：17
- 期：6
- 页码：937-943
- 文件大小：1166 K
摘要
Carbonaceous spherules of millimeter size diameter and found in the upper soils throughout Europe are investigated by TEM, including SAED, HRTEM and EELS, and Raman spectroscopy. The spherules consist primarily of carbon and have an open cell-like internal structure. Most of the carbon appears in an amorphous state, but different morphologies of nano- and microdiamond particles have also been discovered including flake shapes. The latter observation, together with the original findings of some of these spherules in crater-like structures in the landscape and including severely deformed rocks with some spherules being embedded in the fused crust of excavated rocks, points towards unique conditions of origin for these spherules and particles, possibly of exogenic origin.