Hydrothermal and conventional H₃PO₄ activation of two natural bio-fibers

详细信息	查看全文 | 推荐本文 |

• 作者：A.J. Romero-Anaya ; M.A. Lillo-Ró ; denas ; C. Salinas-Martí ; nez de Lecea ; A. Linares-Solano ; ^{linares@ua.es}
• 刊名：Carbon
• 出版年：2012
• 期刊代码：10_00086223
• 类别：ms
• 出版时间：August, 2012
• 卷：50
• 期：9
• 页码：3158-3169
• 文件大小：1120 K

摘要

Two phosphoric acid activation procedures; Activation after Hydrothermal Impregnation (recently published) and Activation after Incipient Wetness Impregnation instead of conventional impregnation are analyzed in two natural bio-fiber precursors: banana pseudostem and coconut fiber matting. Both procedures are compared analyzing, in both precursors, the influence that variables such as H₃PO₄/precursor ratio, activation temperature and impregnation time have on the resulting activated carbons (ACs) properties. The work also pays special attention to the mesoporosity development and the application of these ACs to adsorb gasoline vapors.

Both H₃PO₄ activation procedures develop activated carbons having suitable activation yields and porosity developments, giving the Activation after Incipient Wetness Impregnation method better results than the Activation after Hydrothermal Impregnation. Both natural bio-fibers are good precursors, rendering the coconut fiber matting better results than the banana pseudostem. The variables studied affect the porosity development, being precursor and H₃PO₄/precursor ratio the variables that most affect. By a suitable selection of these variables, activated carbons having high adsorption capacities (BET above 2500 m² g^鈭? and micropore volume above 1.00 cm³ g^鈭?) and well developed mesoporosity (reaching 1.41 cm³ g^鈭?), can be prepared. Most of the samples prepared perform very well for adsorbing gasoline vapors, showing a linear relationship with their resulting volumes.