Synthesis and crystal structure of hydroxyacetophenone Schiff bases containing propargyl moiety: Solvent effects on UV-visible spectra

详细信息	查看全文 | 推荐本文 |

• 作者：V. Selvarani^a ; B. Annaraj^a ; M.A. Neelakantan^a ; ^{maneels@rediffmail.com} ; ^{drmaneelakantan@gmail.com} ; S. Sundaramoorthy^b ; D. Velmurugan^b
• 关键词：Hydroxyacetophenone ; Schiff bases ; Crystal structure ; UV&ndash ; visible spectra ; Solvatochromism
• 刊名：Spectrochimica Acta Part A ; Molecular and Biomolecular Spectroscopy
• 出版年：2012
• 期刊代码：99_13861425
• 类别：ch
• 出版时间：June, 2012
• 卷：91
• 期：Complete
• 页码：329-337
• 文件大小：1095 K

摘要

Four tetradentate (N₂O₂) and tridentate (NO₂) Schiff base compounds (L1-L4) with propargyl moiety were prepared by the condensation of 1-[2-hydroxy-4-(prop-2-yn-1-yloxy)phenyl]ethanone with various aliphatic amines. The newly synthesized compounds (L1-L4) were characterized on the basis of the results of elemental analysis, thermal analysis, FT-IR, ¹H NMR spectroscopic studies and single crystal X-ray crystallography. The different bands observed in the electronic spectra of the compounds in various organic solvents have been assigned to the proper electronic transitions. The hydrogen bonding and tautomeric equilibria in both of solution and the solid state are explained. The solvatochromism of the synthesized compounds in different solvents in the UV-visible spectra are discussed.