Preparation of polystyrene-supported Lewis acidic Fe(III) ionic liquid and its application in catalytic conversion of carbon dioxide

详细信息	查看全文 | 推荐本文 |

• 作者：Jian Gao ; Qing-Wen Song ; Liang-Nian He ; ^{heln@nankai.edu.cn} ; Chang Liu ; Zhen-Zhen Yang ; Xu Han ; Xue-Dong Li ; Qing-Chuan Song
• 关键词：Carbon dioxide ; Iron-containing ionic liquid ; Cycloaddition ; Heterogeneous catalyst ; Cyclic carbonates
• 刊名：Tetrahedron
• 出版年：2012
• 期刊代码：107_00404020
• 类别：ch
• 出版时间：20 May, 2012
• 卷：68
• 期：20
• 页码：3835-3842
• 文件大小：1506 K

摘要

A polystyrene-supported Lewis acidic iron-containing ionic liquid was proved to be recyclable and efficient heterogeneous catalyst for converting CO₂ into cyclic carbonate without utilization of any organic solvent or additive. Excellent yields and selectivity were obtained under mild reaction conditions. Notably, the catalyst could be readily recovered and reused over five times without appreciable loss of catalytic activity. A possible catalytic cycle was proposed. The present protocol has successfully been applied to reactions of aziridines/propargyl amines with CO₂. This kind of the catalyst presented herein would have great potential in industrial application thanks to its featured advantages.