Determination of mercury distribution inside spent compact fluorescent lamps by atomic absorption spectrometry
- 作者：Natalia Rey-Raap ; Antonio Gallardo ; gallardo@emc.uji.es
- 关键词：Atomic absorption spectrometry ; Compact fluorescent lamps ; Phosphor powder ; Hazardous waste
- 刊名：Waste Management
- 出版年：2012
- 期刊代码：70_0956053x
- 类别：env
- 出版时间：May, 2012
- 卷：32
- 期：5
- 页码：944-948
- 文件大小：255 K
摘要
In this study, spent compact fluorescent lamps were characterized to determine the distribution of mercury. The procedure used in this research allowed mercury to be extracted in the vapor phase, from the phosphor powder, and the glass matrix. Mercury concentration in the three phases was determined by the method known as cold vapor atomic absorption spectrometry. Median values obtained in the study showed that a compact fluorescent lamp contained 24.52 卤 0.4 ppb of mercury in the vapor phase, 204.16 卤 8.9 ppb of mercury in the phosphor powder, and 18.74 卤 0.5 ppb of mercury in the glass matrix. There are differences in mercury concentration between the lamps since the year of manufacture or the hours of operation affect both mercury content and its distribution. The 85.76%of the mercury introduced into a compact fluorescent lamp becomes a component of the phosphor powder, while more than 13.66%is diffused through the glass matrix. By washing and eliminating all phosphor powder attached to the glass surface it is possible to classified the glass as a non-hazardous waste.