Direct oxidation of cycloalkanes with molecular oxygen to dicarboxylic acids using isoamyl nitrite

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• 作者：Yuichiro Suzuki ; Emi Harada ; Katsuhisa Nakamaru ; Yasuhisa Takeda ; Makoto Sano ; Keiji Hashimoto ; Takanori Miyake
• 关键词：Isoamyl nitrite ; Oxidation ; Cyclohexane ; Adipic acid
• 刊名：Journal of Molecular Catalysis A ; Chemical
• 出版年：2007
• 期刊代码：57_13811169
• 类别：ch
• 出版时间：17 October 2007
• 卷：276
• 期：1-2
• 页码：1-7
• 文件大小：505 K

摘要

Oxidation of cycloalkanes with molecular oxygen using isoamyl nitrite was examined under mild conditions. Cycloalkanes were easily oxidized with molecular oxygen to give the corresponding cycloalcohols, cycloalkanones and dicarboxylic acids at 120 °C or lower temperatures. The oxidation of the cycloalkanes was promoted by adding soluble Co and Mn ions.