Charles Harvey, Hyun-Hoon Lee and Junggun Oh, The Korean Economy: Post-Crisis Policies, Issues and Prospects , Edgar Elgar Publishing, Inc., Cheltanham, UK (2004) ISBN 1-84376-244-7 xii+324 pp..
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摘要
A clean and simple wet chemical process using dilute aqueous ozone (O3) solution with or without ultrasound (US) was used to functionalize single-walled carbon nanotubes (SWCNTs). Both O3 and O3/US treatments greatly increased the stability of SWCNTs in water. Results of X-ray photoelectron spectroscopy (XPS) showed that the surface oxygen to carbon atomic ratio increased by more than 600%after 72 h of O3 treatment. Moreover, the effective particle size of SWCNTs was reduced from the initial 4400 to not, vert, similar300 and not, vert, similar150 nm, after 24 h of O3 and O3/US treatment, respectively. The zeta potential of treated SWCNTs decreased from 3.0 to −35.0 mV (at pH 4) after 2 h of treatment with both O3 and O3/US. Based on the XPS results, the oxidation pathway was proposed: at the onset of the oxidation reaction, the Cdouble bond; length as m-dashC double bond was first converted to single bondCsingle bondOH which was then oxidized to single bondCdouble bond; length as m-dashO and Odouble bond; length as m-dashCsingle bondOH concurrently. Oxidation reactions could be described well with first order expressions. Treatment time controlled the extent of surface oxidation and subsequently the stability and dispersion of SWCNTs in water.

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