Analysis and characterization of coordination compounds by resonance Raman spectroscopy

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• 作者：Maria Wä ; chtler^a ; ^b ; Julien Guthmuller^c ; Leticia Gonzá ; lez^d ; Benjamin Dietzek^a ; ^b ; ^{benjamin.dietzek@ipht-jena.de}
• 关键词：RR ; resonance Raman ; TR2 ; transient resonance Raman ; TR3 ; time-resolved resonance Raman ; FS(R)RS ; femtosecond time-resolved stimulated (resonance) Raman spectroscopy ; MLCT ; metal-to-ligand charge-transfer ; LLCT ; ligand-to-ligand charge-transfer ; MC ; metal
• 刊名：Coordination Chemistry Reviews
• 出版年：2012
• 期刊代码：27_00108545
• 类别：ch
• 出版时间：August, 2012
• 卷：256
• 期：15-16
• 页码：1479-1508
• 文件大小：2642 K

摘要

Resonance Raman spectroscopy has become a powerful tool to study excited-state geometries, excited-state charge distributions and photoinduced reaction dynamics in coordination compounds. Due to their rich photophysical properties coordination compounds are utilized for a variety of applications ranging from DNA sensing to photocatalysis. This review features recent applications of various resonance Raman scattering techniques to mechanistically study the interplay of geometrical and electronic structure and photoinduced dynamics in coordination compounds.