Unique photoreactivity of mercury(II) 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin

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• 作者：Horvá ; th ; Ottó ; Valicsek ; Zsolt ; Vogler ; Arnd
• 关键词：Photophysics ; Photochemistry ; Charge transfer ; Dissociation ; Metalloporphyrin ; Mercury
• 刊名：Inorganic Chemistry Communications
• 出版年：2004
• 期刊代码：39_13877003
• 类别：ch
• 出版时间：July, 2004
• 卷：7
• 期：7
• 页码：854-857
• 文件大小：196 K

摘要

Deviating from coplanar metalloporphyrins, the photochemistry of the kinetically labile, sitting-atop mercury(II) 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin complex is characterized by irreversible porphyrin ligand to metal charge transfer and reversible dissociation.