The study on crystal-crystal transformation of isotactic poly(1-butene)/poly(1-butene-co-propylene) in-reactor alloy by FTIR

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• 作者：Huafeng Shaop> ; p>p>shaohf0826@msn.comp> ; Lange Li ; Zhaodong Wang ; Aihua He ; Baochen Huang
• 关键词：In-reactor alloy ; Crystal phase transformation ; FTIR ; Crystal structure ; Poly(1-butene)
• 刊名：Materials Letters
• 出版年：2012
• 期刊代码：59_0167577x
• 类别：ms
• 出版时间：15 April, 2012
• 卷：73
• 期：Complete
• 页码：24-27
• 文件大小：676 K

摘要

The isotactic poly(1-butene)/ poly(1-butene-co-propylene) in-reactor alloy was prepared by heterogeneous titanium catalyst system. The differences of crystal phase transformation time, phase transformation rate and phase transformation time between Form I and Form II at a given transformation degree at 25 掳C by fourier transform infrared spectroscopy(FT-IR) were discussed. It can be seen that the transformation from Form II to I of the alloy was significantly accelerated by the increase of propylene structure unit. With the further increase of the content of the propylene unit in the alloy, the transformation may be ignored and Form I can be formed immediately at 25 掳C. The change of the spherulite of pure poly(1-butene) and alloy also be observed and discussed.