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Homogeneous and heterogeneously catalyzed oxidation of <textbox>SO2textbox>
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摘要
Oxidation of tyle="text-decoration:none; color:black" href="/science?_ob=MathURL&_method=retrieve&_udi=B6TFK-4NTB98B-6&_mathId=mml20&_user=10&_cdi=5229&_rdoc=28&_acct=C000050221&_version=1&_userid=10&md5=1e970df50af6fb5b95252e3ffee3e139" title="Click to view the MathML source">SO2tyle="text-decoration:none; color:black" href="/science?_ob=MathURL&_method=retrieve&_udi=B6TFK-4NTB98B-6&_mathId=mml21&_user=10&_cdi=5229&_rdoc=28&_acct=C000050221&_version=1&_userid=10&md5=2c5f25250021be9b893efbba8d8ff7ab" title="Click to view the MathML source">SO3 has been studied experimentally in laboratory flow reactors. The homogeneous oxidation by tyle="text-decoration:none; color:black" href="/science?_ob=MathURL&_method=retrieve&_udi=B6TFK-4NTB98B-6&_mathId=mml22&_user=10&_cdi=5229&_rdoc=28&_acct=C000050221&_version=1&_userid=10&md5=adf5258a1ffdbebd52f02acb302f7c3a" title="Click to view the MathML source">O2 was characterized in the temperature range 1023–1323 K at semi-dry and moist conditions. The reaction was found to be very slow, in agreement with results from literature. The experimental data compared well with modeling predictions using a recently published reaction mechanism for gas-phase tyle="text-decoration:none; color:black" href="/science?_ob=MathURL&_method=retrieve&_udi=B6TFK-4NTB98B-6&_mathId=mml23&_user=10&_cdi=5229&_rdoc=28&_acct=C000050221&_version=1&_userid=10&md5=e1a47fe24a5f607574a827b8ede73c81" title="Click to view the MathML source">SO2 oxidation. The ability of quartz, alumina and iron oxide to catalyze the tyle="text-decoration:none; color:black" href="/science?_ob=MathURL&_method=retrieve&_udi=B6TFK-4NTB98B-6&_mathId=mml24&_user=10&_cdi=5229&_rdoc=28&_acct=C000050221&_version=1&_userid=10&md5=f35e1acd3d3fca3d196b979c00676397" title="Click to view the MathML source">SO2 oxidation was studied in the temperature range 873–1273 K. Quartz was found to be inert to tyle="text-decoration:none; color:black" href="/science?_ob=MathURL&_method=retrieve&_udi=B6TFK-4NTB98B-6&_mathId=mml25&_user=10&_cdi=5229&_rdoc=28&_acct=C000050221&_version=1&_userid=10&md5=86bb589bda3261337bdc4315b5a50ea6" title="Click to view the MathML source">SO2 oxidation, while alumina promoted the oxidation. Iron oxide was found to be a strong oxidation catalyst, in agreement with results from literature.

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