The novel polymeric potassium complex with a new coordination mode of orotic acid [K(bc;b>5b>-Hb>2b>Or)(bc;-Hb>2b>O)]b>nb>: Synthesis and structural characterization

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• 作者：Okan Zafer Yeş ; ilel ; Gö ; khan Kaş ; taş ; ; Orhan B&#xfc ; y&#xfc ; kg&#xfc ; ngö ; r
• 关键词：Orotic acid ; New coordination mode ; Potassium orotate ; Vitamin B13
• 刊名：Inorganic Chemistry Communications
• 出版年：2007
• 期刊代码：39_13877003
• 类别：ch
• 出版时间：August 2007
• 卷：10
• 期：8
• 页码：936-939
• 文件大小：327 K

摘要

Novel polynuclear seven-coordinated potassium complex, [K(bc;b>5b>-Hb>2b>Or)(bc;-Hb>2b>O)]b>nb>(Hb>3b>Or = orotic acid), with the new coordination mode of orotic acid has been prepared and characterized by elemental analysis, FT-IR spectra, X-ray diffraction. The orotate ligand exhibits new coordination mode of bc;b>5b>-ba;O, O: ba;O′, O′: O″ for Hb>2b>Or⁻.