Aminochlorination reaction with N-chlorophthalimide as a new nitrogen/chlorine source resulting in 伪-amino derivatives

详细信息	查看全文 | 推荐本文 |

• 作者：Yu Qian^a ; Xiaoyun Ji^a ; Wei Zhou^a ; Jianlin Han^a ; ^{hanjl@nju.edu.cn} ; Guigen Li^b ; Yi Pan^a ; ^{yipan@nju.edu.cn}
• 关键词：N-Chlorophthalimide ; Aminohalogenation ; 尾-Nitrostyrenes ; 伪-Amino compounds
• 刊名：Tetrahedron
• 出版年：2012
• 期刊代码：107_00404020
• 类别：ch
• 出版时间：5 August, 2012
• 卷：68
• 期：31
• 页码：6198-6203
• 文件大小：474 K

摘要

A commercial available compound, N-chlorophthalimide was reported as an efficient nitrogen/chlorine source for the aminohalogenation of 尾-nitrostyrenes, which tolerates a wide range of 尾-nitrostyrenes substrates with good chemical yields, as well as excellent regioselectivities. The resulted vicinal haloamino nitro products have been converted into several other valuable 伪-amino compounds under simple and mild conditions.