Chiral supramolecular assembly of amino acid bridged zinc bisporphyrin and bidentate ligand

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• 作者：Liu ; Hai-yang ; Hu ; Xi-ming ; Ying ; Xiao ; Liu ; Yi ; Huang ; Jian ; Huang ; Jin-wang ; Tian ; Xuan ; Ji ; Liang-nian
• 关键词：Chiral zinc bis-porphyrin ; Bidentate ligand ; Supramolecular assembly
• 刊名：Materials Science and Engineering ; C
• 出版年：1999
• 期刊代码：63_09284931
• 类别：ms
• 出版时间：December 30, 1999
• 卷：10
• 期：1-2
• 页码：33-38
• 文件大小：235 K

摘要

Coordination behavior of bidentate ligand ethylenediamine with amino acid bridged chiral zinc bisporphyrin o,o-C₂-AA-C₂-(TPP)₂Zn₂ was investigated by circular dichroism (CD), UV–Vis and ¹H-NMR spectroscopy, experimental results suggested that o,o-C₂-AA-C₂-(TPP)₂Zn₂ tend to form linear supramolecular assembly with ethylenediamine in chloroform.