Higher-order structural analysis of bacterial poly[(R)-3-hydroxybutyrate-co-(R)-3-hydroxyhexanote] highly oriented films
- 作者：Jae-Chang Lee ; Akifumi Yasui ; Yeonhwan Jeong ; Shinichi Sakurai ; Hideki Yamane
- 关键词：Bacterial copolyester ; Roll drawing ; Higher-order structure
- 刊名：Polymer
- 出版年：2008
- 期刊代码：83_00323861
- 类别：ms
- 出版时间：29 April 2008
- 卷：49
- 期：9
- 页码：2362-2367
- 文件大小：1229 K
摘要
Bacterial poly[(R)-3-hydroxybutyrate-co-(R)-3-hydroxyhexanoate] (PHBH) highly oriented films were prepared by the combination of roll and uniaxial drawing processes. The change in the higher-order structure of PHBH films was investigated by wide-angle X-ray diffraction (WAXD) and small angle X-ray scattering (SAXS). Extended films, which show superior mechanical properties and high ductility, have complicated structures. By roll extension, both deformed and undeformed spherulites co-exist, the former inclined to the direction perpendicular to the film surface. The latter were destroyed by further uniaxial extension. The tie-molecules between uniaxially oriented lamellae were extended and transformed to the β-form with a planar zig-zag conformation. Three kinds of structures, c-axis parallel to the uniaxial drawing direction, c-axis inclining to the normal vector of the film surface, and the β-form between lamellae, are intermingled in the film.