The charge and orbital ordered states in the single-layered manganite crystals,
Nd1−xSr1+xMnO4(x=0.67,0.75), have been investigated. We have observed the superlattice spots with modulation wave vector,
q=(δ,δ,0),
δ=, [
,] in
x=0.75[0.67] by resonant and non-resonant X-ray scattering. These results show that not only the atomic displacement pattern but also the charge-orbital structure has the unit cell of
4√2a×√2a×c[3√2a×√2a×c].