Preparation of Bimetallic Core-shell Nanoparticles with Magnetically Recyclable and High Catalytic Abilities

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• 作者：Huizhang Guo ; Yuanzhi Chen ; ^{yuanzhi@xmu.edu.cn} ; Xiaozhen Chen ; Laisen Wang ; Hemei Ping ; Dong-Liang Peng ; ^{dlpeng@xmu.edu.cn}
• 关键词：Nanoparticles ; core-shell ; catalysts
• 刊名：Procedia Engineering
• 出版年：2012
• 期刊代码：P56_18777058
• 类别：et
• 出版时间：2012
• 卷：36
• 期：Complete
• 页码：504-509
• 文件大小：444 K

摘要

In this work, we report the preparation of bimetallic core-shell nanoparticles (NPs) using a simple solution synthetic route. A typical example is the Ag@Ni NPs that are synthesized using oleylamine as solvent and reducing agent. The as-obtained Ag@Ni NPs exhibit a spherical morphology and a highly narrow size distribution. Excellent catalytic properties for the H2 generation from dehydrogenation of sodium borohydride in aqueous solutions are observed. Similar synthetic strategies have also been developed for the preparation of other bimetallic core-shell NPs, such as Ag@Co and Cu@Ni NPs. These bimetallic core-shell NPs are promising candidates for novel optical and magnetic materials as well as high-performance catalysts.