A novel lamellar coordination polymer incorporating partially overlapped helices, ladders and zigzag chains – Synthesis, crystal structure and magnetic property

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• 作者：Yang Su ; Shuangquan Zang ; Chunying Duan ; Huizhen Zhu ; Qingjin Meng
• 关键词：Crystal structure ; Multifold motif ; Magnetic property
• 刊名：Inorganic Chemistry Communications
• 出版年：2007
• 期刊代码：39_13877003
• 类别：ch
• 出版时间：March 2007
• 卷：10
• 期：3
• 页码：339-342
• 文件大小：515 K

摘要

The hydrothermal assembly of CoCl₂ · H₂O with benzene-1, 2, 3, 4-tetracarboxylic acid (H₄mpda) yielded a novel lamellar coordination polymeric complex, Co₂mpda(H₂O)₆ · H₂O (1), in which each layer presents an interesting multifold topology: both as partially overlapped helices with alternate chirality and as alternately arranged ladders and zigzag chains.