An Infrared Spectroscopic Study on the Hofmann- and en-Td-typeClathrates: Mn(NH)Zn(CN).2benzene and Mn(ethylenediamine)Zn(CN).2benzene

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• 作者：Kantarci ; Ziya ; Batyak ; Celal ; Kasap ; Ergü ; n
• 关键词：ammonia ; benzene ; ethylenediamine ; H ; bonding of benzene ; inclusion compounds ; IR spectra ; tetracyanozincate ; Hofmann clathrates
• 刊名：Journal of Inclusion Phenomena and Molecular Recognition inChemistry
• 出版时间：2001
• 出版年：2001
• 期刊代码：19_09230750
• 类别：soc
• 卷：39
• 期：1/2
• 页码：103-108
• 数据来源：sp

摘要

Infrared spectra of Mn(NH$\_3$)$\_2$Zn(CN)$\_4$.2C$\_6$H$\_6$ andMn(ethylenediamine)Zn(CN)$\_4$.2C$\_6$H$\_6$ are reported. The spectral data suggest that these compounds are similar in structure toHofmann-T$\_d$-type and the en-T$\_d$-type clathrates,respectively. There is good evidence for H-bonding from ammoniaN–H to benzene as a π to σ H-bond.