Contribution of Pendant Ester Group Hydrolysis to the Erosion of Acrylic Polymers in Binders Aimed at Organotin-Free Antifouling Paints
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- 作者：Karine Vallee-Rehel ; Val茅rie Langlois and Philippe Guerin
- 关键词：Hydrolysis ; erosion ; acrylic acid polymers ; antifouling ; GC ; MS ; coulometry
- 刊名：Journal of Polymers and the Environment
- 出版时间：1998
- 出版年：1998
- 期刊代码：18_15662543
- 类别：phi
- 卷：06
- 期：4
- 页码：175-186
- 数据来源：sp
摘要
Specific polymeric material applications as bioactive molecules delivery systems involve a strictly controlled degradation of polymer matrixes. One possibility to obtain a zero-order kinetic for small molecules release consists in a simple hydrolysis of ester groups contained in the macromolecular structure. The chemical degradation can lead to the continuous surface erosion of the formulated resins without loss of their mechanical properties and to a permanent activity of the delivery systems. Hydrolysis is a very well-known reaction in the case of organic molecules containing ester groups. The mechanism seems to be more complicated when ester groups are located in macromolecular structures. With the aim of antifouling applications, acrylic acid polymers bearing lateral ester groups of different chemical structures (hydrophilic, hydrophobic, hydrolyzable) have been prepared, characterized, and immersed in water, at pH 8, and their hydrolysis has been studied. Experimental data display two parameters, at least, which must be taken into account: the reactivity of the ester groups toward hydrolysis and the hydrophilic/hydrophobic balance of the polymer. The susceptibility of the acrylic polymers to hydrolysis has been compared to the erosion characteristics of the corresponding films. The results confirm that hydrolysis is necessary to obtain a regular degradation of the films without loss of mechanical properties. A relationship has been observed between the characteristics of hydrolysis and erosion for each studied polymer.