Preparation and characterization of nanocrystalline and mesoporous strontium titanate thin films at room temperature
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- 作者：M. R. Mohammadi (1) mrm41@cam.ac.uk
D. J. Fray (2) - 关键词：Strontium titanate – ; Room temperature – ; Sol– ; gel – ; Nanocrystalline
- 刊名：Journal of Coatings Technology and Research
- 出版时间：October 2011
- 出版年：2011
- 期刊代码：20_1935-3804
- 类别：ch
- 卷：8
- 期：5
- 页码：585-593
- 数据来源：sp
摘要
The low temperature perovskite-type strontium titanate (SrTiO3) thin films and powders with nanocrystalline and mesoporous structure were prepared by a straightforward particulate sol–gel route. The prepared sol had a narrow particle size distribution with hydrodynamic diameter of about 17 nm. X-ray diffraction (XRD) revealed that the synthesized powders had a perovskite-SrTiO3 structure with preferable orientation growth along the (1 0 0) direction. TEM images showed that the average crystallite size of the powders annealed in the range 300–800掳C was around 8 nm. FE-SEM analysis and AFM images revealed that the deposited thin films had mesoporous and nanocrystalline structure with the average grain size of 25 nm at 600掳C. Based on Brunauer–Emmett–Taylor (BET) analysis, the synthesized powders showed mesoporous structure with BET surface area in the range 92–75 m2/g at 400–600掳C. One of the smallest crystallite sizes and one of the highest surface areas reported in the literature were obtained, which can be used in many applications, such as photocatalysts.