Calculation of solubility of solid solutes in mixed non-aqueous solvents within the limits of the theory of molecular association
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- 作者：E. D. Totchasov ; M. Yu. Nikiforov and G. A. Al鈥檖er
- 关键词：calculation of solubility ; non ; aqueous solvents ; anthracene ; molecular association
- 刊名：Journal of Structural Chemistry
- 出版时间：May, 2007
- 出版年：2007
- 期刊代码：26_00224766
- 类别：law
- 卷：48
- 期：3
- 页码：474-478
- 数据来源：sp
摘要
A method for calculating the solubility of solid substances in mixed non aqueous solvents is proposed based on the theory of molecular association and a simple lattice model (ASL = Associated Solution + Lattice). This method provides the calculation of the solubility of solids in mixed non aqueous solvents using only the molecular association parameters and the value of the interchange energy ωAB that is derived from the phase equilibrium data in a mixed solvent.