一氧化锰纳米材料的研究进展
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摘要
过去几十年,氧化锰由于其在吸附材料、催化材料和新型磁性材料等领域的广泛应用而受到广发关注,其中一氧化锰纳米颗粒由于其新颖的磁学和电化学性质使其成为研究热点,综述了Mn O纳米材料制备技术的最新进展,系统介绍了微波辐照法、溶胶-凝胶法、溶剂热、气相沉积法、热分解法和固相分解法等,总结了一氧化锰纳米材料在磁共振成像、锂离子电池阳极材料、催化和分子载体的应用,并展望了可能发展的趋势。
In the past decade,manganese oxides have received extensive attention for their wide applications in the adsorption materials,catalyst materials and new magnetic materials,manganese( II) oxide( Mn O) nanomaterials have been a research focus in recent years especially due to their favorable magnetic and electrochemical properties. Many proposals for the synthesis of Mn O nanomaterials using microwave irradiation,sol-gel,solvothermal,vapor phase deposition,thermal decomposition and solid-state thermal decomposition method were summarized. The application of Mn O nanomaterials in MRI,anode material for lithium ion batteries,catalysis and molecular carrier were described. The future development trends were also simply forecasted.
In the past decade,manganese oxides have received extensive attention for their wide applications in the adsorption materials,catalyst materials and new magnetic materials,manganese( II) oxide( Mn O) nanomaterials have been a research focus in recent years especially due to their favorable magnetic and electrochemical properties. Many proposals for the synthesis of Mn O nanomaterials using microwave irradiation,sol-gel,solvothermal,vapor phase deposition,thermal decomposition and solid-state thermal decomposition method were summarized. The application of Mn O nanomaterials in MRI,anode material for lithium ion batteries,catalysis and molecular carrier were described. The future development trends were also simply forecasted.
引文
[1]Ghosh M,Biswas K,Sundaresan A,et al.Mn O and Ni O nanoparticles:synthesis and magnetic properties[J].J.Mater.Chem.,2006,16(1):106-111.
[2]Lu Y,Zhang L,Li J,et al.Mn O Nanocrystals:A Platform for Integration of MRI and Genuine Autophagy Induction for Chemotherapy[J].Adv.Funct.Mater.,2013,23(12):1534-1546.
[3]Zitoun D,Pinna N,Frolet N,et al.Single crystal manganese oxide multipods by oriented attachment[J].J.Am.Chem.Soc.,2005,127(43):15034-15035.
[4]Ould-Ely T,Prieto-Centurion D,Kumar A,et al.Manganese(II)oxide nanohexapods:Insight into controlling the form of nanocrystals[J].Chem.Mater.,2006,18(7):1821-1829.
[5]Xie S,Zhou X,Han X,et al.Supercrystals from Crystallization of Octahedral Mn O Nanocrystals[J].J.Phys.Chem.C,2009,113(44):19107-19111.
[6]Chang Y Q,Yu D P,Wang Z,et al.Fabrication and abnormal magnetic properties of Mn O nanoparticles via vapor phase growth[J].J.Cryst.Growth,2005,281(2-4):678-682.
[7]Banis M N,Zhang Y,Banis H N,et al.Controlled synthesis and characterization of single crystalline Mn O nanowires and Mn-Si oxide heterostructures by vapor phase deposition[J].Chem.Phys.Lett.,2011,501(4-6):470-474.
[8]Tai K,Sun K,Huang B,et al.Catalyzed oxidation for nanowire growth[J].Nanotechnology,2014,25(14):145603.
[9]Ghosh M,Biswas K,Sundaresan A,et al.Mn O and Ni O nanoparticles:synthesis and magnetic properties[J].J.Mater.Chem.,2006,16(1):106-111.
[10]Zheng M T,Zhang H R,Gong X B,et al.A simple additive-free approach for the synthesis of uniform manganese monoxide nanorods with large specific surface area[J].Nanoscale Res.Lett.,2013,8:166.
[11]Moorhead-Rosenberg Z,Harrison K L,Turner T,et al.A rapid microwave-assisted solvothermal approach lower-valent transition metal oxides[J].Inorg.Chem.,2013,52:13087-13093.
[12]Park J,Kang E A,Bae C J,et al.Synthesis,characterization,and magnetic properties of uniform-sized Mn O nanospheres and nanorods[J].J.Phys.Chem.B,2004,108(36):13594-13598.
[13]Si H,Wang H,Shen H,et al.Controlled synthesis of monodisperse manganese oxide nanocrystals[J].Cryst Eng Comm,2009,11(6):1128-1132.
[14]Lin C C,Chen C J,Chiang R K.Facile synthesis of monodisperse Mn O nanoparticles from bulk Mn O[J].J.Cryst.Growth,2012,338(1):152-156.
[15]Shanmugam S,Gedanken A.Mn O octahedral nanocrystals and Mn O@C core-shell composites:Synthesis,characterization,and electrocatalytic properties[J].J.Phys.Chem.B,2006,110(48):24486-24491.
[16]Chen L,Xing H,Shen Y,et al.Solid-state thermolysis of Mn O(12)containing molecular clusters into novel Mn O nano-and microparticles[J].J.Solid State Chem.,2009,182(6):1387-1395.
[17]Na H B,Lee J H,An K,et al.Development of a T-1 contrast agent for magnetic resonance imaging using Mn O nanoparticles[J].Angew.Chem.,Int.Ed.,2007,46(28):5397-5401.
[18]Huang J,Xie J,Chen K,et al.HSA coated Mn O nanoparticles with prominent MRI contrast for tumor imaging[J].Chem.Commun.,2010,46(36):6684-6686.
[19]Schladt T D,Shukoor M I,Schneider K,et al.Au@Mn O Nanoflowers:Hybrid Nanocomposites for Selective Dual Functionalization and Imaging[J].Angew.Chem.,Int.Ed.,2010,49(23):3976-3980.
[20]Bennewitz M F,Lobo T L,Nkansah M K,et al.Biocompatible and p H-Sensitive PLGA Encapsulated Mn O Nanocrystals for Molecular and Cellular MRI[J].Acs Nano,2011,5(5):3438-3446.
[21]Hu X Q,Ji Y X,Wang M L,et al.Water-Soluble and Biocompatible Mn O@PVP Nanoparticles for MR Imaging In Vitro and In Vivo[J].J.Biomed.Nanotechnol.,2015,9(6):976-984.
[22]Zhang K,Han P,Gu L,et al.Synthesis of Nitrogen-Doped Mn O/Graphene Nanosheets Hybrid Material for Lithium Ion Batteries[J].ACS Appl.Mater.Interfaces,2012,4(2):658-664.
[23]Chen W M,Qie L,Shen Y,et al.Superior lithium storage performance in nanoscaled Mn O promoted by N-doped carbon webs[J].Nano Energy,2013,2(3):412-418.
[24]Jiang H,Hu Y,Guo S,et al.Rational Design of Mn O/Carbon Nanopeapods with Internal Void Space for High-Rate and Long-Life Li-Ion Batteries[J].ACS Nano,2014,8(6):6038-6046.
[25]Guo W,Li X,Ng D H L,et al.Integration of Mn O@graphene with graphene networks towards Li-ion battery anodes[J].RSC Advances,2015,5(117):96681-96684.
[26]Shanmugam S,Gedanken A.Mn O octahedral nanocrystals and Mn O@C core-shell composites:Synthesis,characterization,and electrocatalytic properties[J].J.Phys.Chem.B,2006,110(48):24486-24491.
[27]Li J,He X W,Wei X J,et al.Ag embeded Mn O nanorod:facile synthesis and oxygen reduction[J].Cryst Eng Comm,2015,17:7646-7652.
[28]Xing R,Liu G,Quan Q,et al.Functional Mn O nanoclusters for efficient siRNA delivery[J].Chem.Commun.,2011,47(44):12152-12154.
[29]Howell M,Mallela J,Wang C,et al.Manganese-loaded lipidmicellar theranostics ofr simultaneous drug and gene delivery to lungs[J].J.Control Release,2013,167(2):210.
[2]Lu Y,Zhang L,Li J,et al.Mn O Nanocrystals:A Platform for Integration of MRI and Genuine Autophagy Induction for Chemotherapy[J].Adv.Funct.Mater.,2013,23(12):1534-1546.
[3]Zitoun D,Pinna N,Frolet N,et al.Single crystal manganese oxide multipods by oriented attachment[J].J.Am.Chem.Soc.,2005,127(43):15034-15035.
[4]Ould-Ely T,Prieto-Centurion D,Kumar A,et al.Manganese(II)oxide nanohexapods:Insight into controlling the form of nanocrystals[J].Chem.Mater.,2006,18(7):1821-1829.
[5]Xie S,Zhou X,Han X,et al.Supercrystals from Crystallization of Octahedral Mn O Nanocrystals[J].J.Phys.Chem.C,2009,113(44):19107-19111.
[6]Chang Y Q,Yu D P,Wang Z,et al.Fabrication and abnormal magnetic properties of Mn O nanoparticles via vapor phase growth[J].J.Cryst.Growth,2005,281(2-4):678-682.
[7]Banis M N,Zhang Y,Banis H N,et al.Controlled synthesis and characterization of single crystalline Mn O nanowires and Mn-Si oxide heterostructures by vapor phase deposition[J].Chem.Phys.Lett.,2011,501(4-6):470-474.
[8]Tai K,Sun K,Huang B,et al.Catalyzed oxidation for nanowire growth[J].Nanotechnology,2014,25(14):145603.
[9]Ghosh M,Biswas K,Sundaresan A,et al.Mn O and Ni O nanoparticles:synthesis and magnetic properties[J].J.Mater.Chem.,2006,16(1):106-111.
[10]Zheng M T,Zhang H R,Gong X B,et al.A simple additive-free approach for the synthesis of uniform manganese monoxide nanorods with large specific surface area[J].Nanoscale Res.Lett.,2013,8:166.
[11]Moorhead-Rosenberg Z,Harrison K L,Turner T,et al.A rapid microwave-assisted solvothermal approach lower-valent transition metal oxides[J].Inorg.Chem.,2013,52:13087-13093.
[12]Park J,Kang E A,Bae C J,et al.Synthesis,characterization,and magnetic properties of uniform-sized Mn O nanospheres and nanorods[J].J.Phys.Chem.B,2004,108(36):13594-13598.
[13]Si H,Wang H,Shen H,et al.Controlled synthesis of monodisperse manganese oxide nanocrystals[J].Cryst Eng Comm,2009,11(6):1128-1132.
[14]Lin C C,Chen C J,Chiang R K.Facile synthesis of monodisperse Mn O nanoparticles from bulk Mn O[J].J.Cryst.Growth,2012,338(1):152-156.
[15]Shanmugam S,Gedanken A.Mn O octahedral nanocrystals and Mn O@C core-shell composites:Synthesis,characterization,and electrocatalytic properties[J].J.Phys.Chem.B,2006,110(48):24486-24491.
[16]Chen L,Xing H,Shen Y,et al.Solid-state thermolysis of Mn O(12)containing molecular clusters into novel Mn O nano-and microparticles[J].J.Solid State Chem.,2009,182(6):1387-1395.
[17]Na H B,Lee J H,An K,et al.Development of a T-1 contrast agent for magnetic resonance imaging using Mn O nanoparticles[J].Angew.Chem.,Int.Ed.,2007,46(28):5397-5401.
[18]Huang J,Xie J,Chen K,et al.HSA coated Mn O nanoparticles with prominent MRI contrast for tumor imaging[J].Chem.Commun.,2010,46(36):6684-6686.
[19]Schladt T D,Shukoor M I,Schneider K,et al.Au@Mn O Nanoflowers:Hybrid Nanocomposites for Selective Dual Functionalization and Imaging[J].Angew.Chem.,Int.Ed.,2010,49(23):3976-3980.
[20]Bennewitz M F,Lobo T L,Nkansah M K,et al.Biocompatible and p H-Sensitive PLGA Encapsulated Mn O Nanocrystals for Molecular and Cellular MRI[J].Acs Nano,2011,5(5):3438-3446.
[21]Hu X Q,Ji Y X,Wang M L,et al.Water-Soluble and Biocompatible Mn O@PVP Nanoparticles for MR Imaging In Vitro and In Vivo[J].J.Biomed.Nanotechnol.,2015,9(6):976-984.
[22]Zhang K,Han P,Gu L,et al.Synthesis of Nitrogen-Doped Mn O/Graphene Nanosheets Hybrid Material for Lithium Ion Batteries[J].ACS Appl.Mater.Interfaces,2012,4(2):658-664.
[23]Chen W M,Qie L,Shen Y,et al.Superior lithium storage performance in nanoscaled Mn O promoted by N-doped carbon webs[J].Nano Energy,2013,2(3):412-418.
[24]Jiang H,Hu Y,Guo S,et al.Rational Design of Mn O/Carbon Nanopeapods with Internal Void Space for High-Rate and Long-Life Li-Ion Batteries[J].ACS Nano,2014,8(6):6038-6046.
[25]Guo W,Li X,Ng D H L,et al.Integration of Mn O@graphene with graphene networks towards Li-ion battery anodes[J].RSC Advances,2015,5(117):96681-96684.
[26]Shanmugam S,Gedanken A.Mn O octahedral nanocrystals and Mn O@C core-shell composites:Synthesis,characterization,and electrocatalytic properties[J].J.Phys.Chem.B,2006,110(48):24486-24491.
[27]Li J,He X W,Wei X J,et al.Ag embeded Mn O nanorod:facile synthesis and oxygen reduction[J].Cryst Eng Comm,2015,17:7646-7652.
[28]Xing R,Liu G,Quan Q,et al.Functional Mn O nanoclusters for efficient siRNA delivery[J].Chem.Commun.,2011,47(44):12152-12154.
[29]Howell M,Mallela J,Wang C,et al.Manganese-loaded lipidmicellar theranostics ofr simultaneous drug and gene delivery to lungs[J].J.Control Release,2013,167(2):210.