红外和拉曼光谱分析方法在毒品检测中的应用
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摘要
与传统的色谱分析方法相比较,光谱分析方法不仅准确高效,而且操作简单便捷,无毒无害,对操作者和环境保护更加友好。随着傅里叶变换红外光谱和表面增强拉曼技术等方法的发展和不断完善,光谱分析方法在毒品检测和海关、边境安检等领域也得到越来越广泛的应用。该文在调研大量国内外文献的基础上,对以红外和拉曼光谱技术为代表的光谱分析方法在毒品检测中的应用情况和研究成果作以分析介绍,认为光谱分析方法未来发展前景广阔,有望掀起毒检领域的一场技术革新。
Compared with traditional chromatographic methods,spectral analysis is not only accurate and efficient,but also simple and convenient,non-toxic and harmless,and is more friendly to operators and environmental protection.With the development and improvement of Fourier transform infrared spectrum and surface enhancement Raman technology,spectral analysis is widely used in drug detection and other fields.Based on a large number of domestic and foreign literatures,this paper introduces the application of infrared spectrometry and Raman spectrometry in drug detection and the research achievements.It is expected to raise a technical innovation in the field of drug detection.
Compared with traditional chromatographic methods,spectral analysis is not only accurate and efficient,but also simple and convenient,non-toxic and harmless,and is more friendly to operators and environmental protection.With the development and improvement of Fourier transform infrared spectrum and surface enhancement Raman technology,spectral analysis is widely used in drug detection and other fields.Based on a large number of domestic and foreign literatures,this paper introduces the application of infrared spectrometry and Raman spectrometry in drug detection and the research achievements.It is expected to raise a technical innovation in the field of drug detection.
引文
[1]刘景宁.当前我国毒品犯罪的现状与趋势[J].中国公共安全(学术版),2012,(1):95-99.
[2]Jorgenson J W,Dearman Lukacs K.Zone electrophoresis in open-tubular glass capillaries:preliminary data on performance[J].Sep Sci,2015,4(5):230-231.
[3]Penido C A,Pacheco M,Lednev K.Raman spectroscopy in Forensic analysis:identification of cocaine and other illegal drugs of abuse[J].Raman Spectroscopy,2016(47):28-38.
[4]徐鹏,郑珲,高利生.红外光谱技术在毒品分析中的研究进展[J].中国药物依赖性杂志,2010,19(2):94-96.
[5]张金庄.基于红外光谱无损检测自封袋表面微量毒品的研究[J].中国人民公安大学学报(自然科学版),2013,(1):14-16.
[6]吴国萍,相秉仁.近红外光谱法非破坏性同时测定海洛因、O6-单乙酰吗啡、乙酰可待因[J].分析化学,2007,35(4):552-554.
[7]吴国萍,相秉仁.近红外光谱技术应用于摇头丸中MDMA、MA无损定量分析的研究[J].分析测试学报,2007,26(5):698-701.
[8]吴国萍,左跃先.近红外漫反射光谱法在毒品同一来源认定中的应用[J].中国药科大学学报,2008,39(4):321-323.
[9]曹槐,路帆,李虹,等.不同来路海洛因近红外光谱的支持向量机模式识别[J].计算机与应用化学,2009,26(3):287-291.
[10]梁宇华.可卡因的定性定量分析[J].广东公安科技,2008,(1):17-20.
[11]王继芬,余静,孙兴龙.红外吸收光谱法快速分析甲基苯丙胺毒品中的添加成分[J].光散射学报,2010,22(4):399-403.
[12]王继芬,王定方,孙兴龙,等.氯胺酮毒品及其添加成分的红外光谱库的建立与应用研究[J].中国人民公安大学学报(自然科学版),2010,(4):11-14.
[13]徐鹏,曹珍年,钱振华,等.海洛因及其盐型的红外光谱分析[J].中国药物依赖性杂志,2010,19(6):493-496.
[14]徐鹏,曹珍年,石慧霞,等.红外光谱技术在毒品分析中的应用[J].刑事技术,2011,(4):47-50.
[15]张润生,王跨陡,龚飞君,等.苯丙胺类毒品及其衍生物的气相色谱-红外光谱分析[J].分析化学,2012,40(6):915-919.
[16]Mak J S W,Rutledge S A,Abu Ghazalah R M,et al.Recent developments in optofluidic assisted Raman spectroscopy[J].Progress in Quantum Electronics,2013,(1):1-50.
[17]吴清华,张振宇.拉曼光谱技术在法庭科学领域中的应用[J].云南警官学院学报,2017,(4):111-116.
[18]Settle F A.Handbook of instrumental techniques for analytical chemistry[M].New Jersey:Prentice Hall Inc,1997:198-201.
[19]Negrusz A,Cooper G.Clarke's Analytical Forensic Toxicology[M].London:Pharmaceutical Press,2013:518-533.
[20]王继芬,余静,孙兴龙,等.毒品及其常见添加成分的拉曼光谱快速分析[J].光散射学报,2012,24(3):312-315.
[21]Ryder A G,O'Connor G M,Glynn T J.Quantitative analysis of cocaine in solid mixtures using Raman spectroscopy and chemometric methods[J].Raman Spectroscopy,2000(31):221-227.
[22]Penido C A,Silveira L,Pacheco M T.Quantification of binary mixtures of cocaine and adulterants using dispersive Raman and FT-IR spectroscopy and principal component regression[J].Instrumentation Science&Technology,2012,(40):441-456.
[23]王清华,王尧,王燕军.拉曼光谱快速定性分析合成毒品[J].刑事技术,2014,(5):33-34.
[24]Bumbrah G C,Sharma R M.Raman spectroscopy-Basic principle,instrumentation and selected applications for the characterization of drug of abuse[J].Egyption Journal of Forensic Sciences,2016,(6):209-215.
[25]Weston R G.Quick screening of crystal methamphetamine/methyl sulfone exhibits by Raman spectroscopy[J].Forensic Science,2010,(4):1068-1075.
[26]Dong R L,Weng S Z,Yang L B,et al.Detection and direct readout of drugs in human urine using dynamic surfaceenhanced Raman spectroscopy and support vector machines[J].Analytical Chemistry,2015,87(5):2937-2944.
[27]Subaihi A,Muhamadali H,Mutter S T,et al.Quantitative detection of codeine in human plasma using surfaceenhanced Raman scattering via adaptation of the isotopic labelling principle[J].Analyst,2017,142(7):1099-1105.
[28]Han Z Z,Liu H L,Wang B,et al.Three dimensional surface-enhanced Raman scattering hotspots in spherical colloidal superstructure for identification and detection of drugs in human urine[J].Analytical Chemistry,2015,87(9):4821-4828.
[29]赵璟悠,王勇,张冠男.拉曼光谱技术在毒品检测应用中的研究进展[J].中国刑警学院学报,2018,(3):116:120.
[30]李树平,解启文,张莉.基于便携式拉曼光谱仪的疑似吸毒人员尿液中毒品的SERS快速检测[J].光散射学报,2018,30(2):115-119.
[31]Olds W J,Jaatinen E,Fredericks P,et al.Spatially offset Raman spectroscopy(SORS)for the analysis and detection of packaged pharmaceuticals and concealed drugs[J].Forensic Science Internaional,2011,(212):69-73.
[32]Matousek P.Inverse spatially offset Raman spectroscopy for deep noninvasive probing of turbid media[J].Applied Spectroscopy,2006,(11):1341-1347.
[2]Jorgenson J W,Dearman Lukacs K.Zone electrophoresis in open-tubular glass capillaries:preliminary data on performance[J].Sep Sci,2015,4(5):230-231.
[3]Penido C A,Pacheco M,Lednev K.Raman spectroscopy in Forensic analysis:identification of cocaine and other illegal drugs of abuse[J].Raman Spectroscopy,2016(47):28-38.
[4]徐鹏,郑珲,高利生.红外光谱技术在毒品分析中的研究进展[J].中国药物依赖性杂志,2010,19(2):94-96.
[5]张金庄.基于红外光谱无损检测自封袋表面微量毒品的研究[J].中国人民公安大学学报(自然科学版),2013,(1):14-16.
[6]吴国萍,相秉仁.近红外光谱法非破坏性同时测定海洛因、O6-单乙酰吗啡、乙酰可待因[J].分析化学,2007,35(4):552-554.
[7]吴国萍,相秉仁.近红外光谱技术应用于摇头丸中MDMA、MA无损定量分析的研究[J].分析测试学报,2007,26(5):698-701.
[8]吴国萍,左跃先.近红外漫反射光谱法在毒品同一来源认定中的应用[J].中国药科大学学报,2008,39(4):321-323.
[9]曹槐,路帆,李虹,等.不同来路海洛因近红外光谱的支持向量机模式识别[J].计算机与应用化学,2009,26(3):287-291.
[10]梁宇华.可卡因的定性定量分析[J].广东公安科技,2008,(1):17-20.
[11]王继芬,余静,孙兴龙.红外吸收光谱法快速分析甲基苯丙胺毒品中的添加成分[J].光散射学报,2010,22(4):399-403.
[12]王继芬,王定方,孙兴龙,等.氯胺酮毒品及其添加成分的红外光谱库的建立与应用研究[J].中国人民公安大学学报(自然科学版),2010,(4):11-14.
[13]徐鹏,曹珍年,钱振华,等.海洛因及其盐型的红外光谱分析[J].中国药物依赖性杂志,2010,19(6):493-496.
[14]徐鹏,曹珍年,石慧霞,等.红外光谱技术在毒品分析中的应用[J].刑事技术,2011,(4):47-50.
[15]张润生,王跨陡,龚飞君,等.苯丙胺类毒品及其衍生物的气相色谱-红外光谱分析[J].分析化学,2012,40(6):915-919.
[16]Mak J S W,Rutledge S A,Abu Ghazalah R M,et al.Recent developments in optofluidic assisted Raman spectroscopy[J].Progress in Quantum Electronics,2013,(1):1-50.
[17]吴清华,张振宇.拉曼光谱技术在法庭科学领域中的应用[J].云南警官学院学报,2017,(4):111-116.
[18]Settle F A.Handbook of instrumental techniques for analytical chemistry[M].New Jersey:Prentice Hall Inc,1997:198-201.
[19]Negrusz A,Cooper G.Clarke's Analytical Forensic Toxicology[M].London:Pharmaceutical Press,2013:518-533.
[20]王继芬,余静,孙兴龙,等.毒品及其常见添加成分的拉曼光谱快速分析[J].光散射学报,2012,24(3):312-315.
[21]Ryder A G,O'Connor G M,Glynn T J.Quantitative analysis of cocaine in solid mixtures using Raman spectroscopy and chemometric methods[J].Raman Spectroscopy,2000(31):221-227.
[22]Penido C A,Silveira L,Pacheco M T.Quantification of binary mixtures of cocaine and adulterants using dispersive Raman and FT-IR spectroscopy and principal component regression[J].Instrumentation Science&Technology,2012,(40):441-456.
[23]王清华,王尧,王燕军.拉曼光谱快速定性分析合成毒品[J].刑事技术,2014,(5):33-34.
[24]Bumbrah G C,Sharma R M.Raman spectroscopy-Basic principle,instrumentation and selected applications for the characterization of drug of abuse[J].Egyption Journal of Forensic Sciences,2016,(6):209-215.
[25]Weston R G.Quick screening of crystal methamphetamine/methyl sulfone exhibits by Raman spectroscopy[J].Forensic Science,2010,(4):1068-1075.
[26]Dong R L,Weng S Z,Yang L B,et al.Detection and direct readout of drugs in human urine using dynamic surfaceenhanced Raman spectroscopy and support vector machines[J].Analytical Chemistry,2015,87(5):2937-2944.
[27]Subaihi A,Muhamadali H,Mutter S T,et al.Quantitative detection of codeine in human plasma using surfaceenhanced Raman scattering via adaptation of the isotopic labelling principle[J].Analyst,2017,142(7):1099-1105.
[28]Han Z Z,Liu H L,Wang B,et al.Three dimensional surface-enhanced Raman scattering hotspots in spherical colloidal superstructure for identification and detection of drugs in human urine[J].Analytical Chemistry,2015,87(9):4821-4828.
[29]赵璟悠,王勇,张冠男.拉曼光谱技术在毒品检测应用中的研究进展[J].中国刑警学院学报,2018,(3):116:120.
[30]李树平,解启文,张莉.基于便携式拉曼光谱仪的疑似吸毒人员尿液中毒品的SERS快速检测[J].光散射学报,2018,30(2):115-119.
[31]Olds W J,Jaatinen E,Fredericks P,et al.Spatially offset Raman spectroscopy(SORS)for the analysis and detection of packaged pharmaceuticals and concealed drugs[J].Forensic Science Internaional,2011,(212):69-73.
[32]Matousek P.Inverse spatially offset Raman spectroscopy for deep noninvasive probing of turbid media[J].Applied Spectroscopy,2006,(11):1341-1347.