水滑石阻燃剂的离子改性研究进展
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摘要
由于水滑石具有层板阳离子可调控、层间阴离子可交换、酸碱性等独特的性能,在医药、离子交换、催化、材料阻燃等领域备受研究者关注。特别是水滑石用作阻燃材料时,具有无卤、无毒、不产生有毒和腐蚀性气体、阻燃和抑烟性能优良等突出优点,已成为当前材料阻燃领域研究的热点。然而,水滑石也存在热稳定性较差、容易聚集、分散性较差等缺点,故国内外学者开展了水滑石阻燃剂改性的系列研究。本文阐述了近年来利用Ca~(2+)、Mg~(2+)、Al~(3+)等阳离子以及BO_3~(3-)、SiO_3~(2-)等阴离子对水滑石阻燃剂进行改性等方面的研究进展,并对水滑石在生物质材料阻燃、低成本水滑石阻燃剂的合成、水滑石协效阻燃剂的研究、水滑石阻燃剂工业化生产新工艺与设备、洁净化制备技术等方面的研究与应用前景进行了展望。
Hydrotalcite is a new class of inorganic materials. Since it has the characteristics of laminate cations adjustable,interlayer anion exchangable and acid-base property, hydrotalcite have received much attention of researchers in many fields such as medicine,ion exchange,reaction catalysis,and material flame retardant. The unique physical and chemical properties make it to be a outstanding flame retardant material with the advantages such as halogen-free,produce non-toxic and corrosive gases,flame retardant and smoke suppression. Study on ion-modified hydrotalcite is becoming a hot spot in the research of flame retardant materials. However,it also has shortcomings such as low thermal stability,easy-reaggregation and poor dispersion. Therefore,domestic and foreign scholars have carried out some research on hydrotalcite modification. This review mainly expounds the research progress in the cationic modification and anion modification of hydrotalcite flame retardants in recent years. The research and application prospects of hydrotalcite in the biomass material flame retardant,synthesis of low-cost hydrotalcite flame retardant,hydrotalcite synergistic flame retardant,new process and equipment,clean preparation technology for hydrotalcite flame retardant industrial production and other aspects are prospected.
Hydrotalcite is a new class of inorganic materials. Since it has the characteristics of laminate cations adjustable,interlayer anion exchangable and acid-base property, hydrotalcite have received much attention of researchers in many fields such as medicine,ion exchange,reaction catalysis,and material flame retardant. The unique physical and chemical properties make it to be a outstanding flame retardant material with the advantages such as halogen-free,produce non-toxic and corrosive gases,flame retardant and smoke suppression. Study on ion-modified hydrotalcite is becoming a hot spot in the research of flame retardant materials. However,it also has shortcomings such as low thermal stability,easy-reaggregation and poor dispersion. Therefore,domestic and foreign scholars have carried out some research on hydrotalcite modification. This review mainly expounds the research progress in the cationic modification and anion modification of hydrotalcite flame retardants in recent years. The research and application prospects of hydrotalcite in the biomass material flame retardant,synthesis of low-cost hydrotalcite flame retardant,hydrotalcite synergistic flame retardant,new process and equipment,clean preparation technology for hydrotalcite flame retardant industrial production and other aspects are prospected.
引文
[1]周良芹,付大友,袁东.四川理工学院学报(自科版),2013,26(5):1~6.
[2]姚潇翎,滑亚婷,杜春贵等.林产工业,2018,2:39~53.
[3]陈君,张勤勇,宋影伟等.西华大学学报(自然科学版),2014(5):64~69.
[4]朱玉刚,董延茂.塑料工业,2012,40(4):19~22.
[5]刘齐鲁.中国非金属矿工业导刊,2017,2:9~11.
[6]K Chibwe,W Jones.Chem.Commun.,1989,14(14):926~927.
[7]C Taviot-Guého,V Prévot,C Forano et al.Adv.Funct.Mater.,2018,28(27):1703868.
[8]顾怡冰,马邕文,万金泉等.环境科学,2016,37(3):1000~1007.
[9]张辉,陆嘉炜,余剑清等.广州化工,2017,45(8):69~72.
[10]周维友,潘九高,吴中等.常州大学学报(自然科学版),2016,28(4):1~6.
[11]J C Buffet,C F Byles,R Felton et al.Chem.Commun.,2016,52(21):4076~4079.
[12]G Zhang,P Ding,M Zhang et al.Polym.Degrad.Stab.,2007,92(9):1715~1720.
[13]E N Kalali,S D Juan,X Wang et al.J.Ther.Anal.Calorim.,2015,121(2):619~626.
[14]王军正,李旭光,苏俏俏.科学与财富,2014(6):101~103.
[15]江平,蒋志城.浙江树人大学学报:自然科学版,2006,(2):37~40.
[16]A Verma,C K Phua,W Y Sim et al.Medicine,2016,95(26):e3996.
[17]张治青,廖梦尘,曾虹燕等.光谱学与光谱分析,2015,35(1):14~18.
[18]李冰,王奖,贾美林等.工业催化,2016,24(10):1~7.
[19]叶江涛,章琛,陈富强等.塑料工业,2018,(2):71~75.
[20]蔺道雷,田国峰,武德珍.中国塑料,2016,30(11):8~12.
[21]倪哲明,张连阳,夏盛杰等.稀有金属材料与工程,2016(s1):159~164.
[22]Q Kong,T Wu,J Wang et al.J.Nanosci.Nanotechnol.,2018,18(5):3660~3665.
[23]黄志义,武斌,康诚等.浙江大学学报(工学版),2016,50(1):27~32.
[24]陈艺兰,林琅,肖荔人等.中国塑料,2008(2):28~32.
[25]陈艺兰,肖良建,陈荣国等.中国塑料,2010,24(8):75~80.
[26]A A Bakr,G Eshaq,A M Rabie et al.Desalin.Water Treat.,2016,57(27):12632~12643.
[27]P H Chang,Y P Chang,Y H Lai et al.J.Alloys Compd.,2014,586:S498~S505.
[28]陈江超.中国科学院过程工程研究所硕士学位论文,2009.
[29]赵晓嫣.山东化工,2011,40(6):33~34.
[30]崔益顺.无机盐工业,2017,49(9):38~41.
[31]刘家伟,王容,李盈颖等.科技创新与应用,2017(16):19~20.
[32]戴昉纳,赵伟,由婷等.精细与专用化学品,2007,15(2):5~8.
[33]Y Y Ding,L Xu,G S Hu.Chin.Sci.Bull.,2011,56(35):3878~3883.
[34]Y X Yan,X Y Gu,L M Li et al.Fibers Polym.,2017,18(11):2060~2069.
[35]田雪梅.塑料助剂,2011,(6):13~15.
[36]童孟良,周芝兰,许沅沅.化工文摘,2008,(2):45~48.
[37]邵长生,沈钟,陈丽特等.塑料工业,1988,(6):40~43.
[38]尚松川,杨保俊,张睿辰等.复合材料学报,2017,34(8):1667~1673.
[39]S Majoni.J.Ther.Anal.Calorim.,2015,120(2):1435~1443.
[40]徐敏虹,潘国祥,陈海锋等.矿物学报,2017,37(4):395~400.
[41]S D Jiang,Z M Bai,G Tang et al.ACS Appl.Mater.Interf.,2014,6(16):14076~14086.
[42]林苗,郑利民.印染,2000,26(9):44~45.
[43]赵博,赵晓云,邹璐等.塑料助剂,2010,(3):6~8.
[44]张月琴,叶旭初.塑料科技,2007,35(9):110~113.
[45]冷尔唯,龚勋,张扬等.化工学报,2018,69(1):239~248.
[46]周卫平,吕秉玲.无机盐工业,1988,(3):16~18.
[47]L L Yu,F Lu,D C Qin et al.Wood Fiber Sci.,2017,49(2):125~133.
[48]李空.中国地质大学(北京)硕士学位论文,2016.
[49]G Varga,S Muráth,Bajcsi et al.React.Kinet.Mech.Cat.,2017,121(1):241~254.
[50]王娜,仲剑初,王洪志.无机盐工业,2016,48(1):25~27,48.
[51]贾修伟,刘治国.化工进展,2003,22(8):818~822.
[52]滕广远,陈俊宏.化工时刊,2018(4):28~32.
[53]郭文珊,勇雪.河南科技,2017(20):59~62.
[54]徐斌,余国民,刘海洋等.山东化工,2017,46(9):18~20.
[55]董珂.东北林业大学硕士学位论文,2016.
[56]但世辉,陈莉莉.化学教育,2012,33(3):71~72.
[57]宋真富.上海师范大学硕士学位论文,2015.
[58]M Shamsayei,Y Yamini,H Asiabi et al.Microchim.Acta,2018,185(3):192.
[59]L Li,W Gu,J Liu et al.Nano Res.,2015,8(2):682~694.
[60]Z Zhang,X Mei,C Xu et al.Sci.Chin.B,2005,48(2):107~114.
[61]Y Gao,Q Wang,J Wang et al.ACS Appl.Mater.Interf.,2014,6(7):5094~5104.
[62]X S Liu,X Y Gu,S Zhang et al.J.Appl.Polym.Sci.,2014,130(5):3645~3651.
[63]立青.中国人造板,2018,25(7):39.
[2]姚潇翎,滑亚婷,杜春贵等.林产工业,2018,2:39~53.
[3]陈君,张勤勇,宋影伟等.西华大学学报(自然科学版),2014(5):64~69.
[4]朱玉刚,董延茂.塑料工业,2012,40(4):19~22.
[5]刘齐鲁.中国非金属矿工业导刊,2017,2:9~11.
[6]K Chibwe,W Jones.Chem.Commun.,1989,14(14):926~927.
[7]C Taviot-Guého,V Prévot,C Forano et al.Adv.Funct.Mater.,2018,28(27):1703868.
[8]顾怡冰,马邕文,万金泉等.环境科学,2016,37(3):1000~1007.
[9]张辉,陆嘉炜,余剑清等.广州化工,2017,45(8):69~72.
[10]周维友,潘九高,吴中等.常州大学学报(自然科学版),2016,28(4):1~6.
[11]J C Buffet,C F Byles,R Felton et al.Chem.Commun.,2016,52(21):4076~4079.
[12]G Zhang,P Ding,M Zhang et al.Polym.Degrad.Stab.,2007,92(9):1715~1720.
[13]E N Kalali,S D Juan,X Wang et al.J.Ther.Anal.Calorim.,2015,121(2):619~626.
[14]王军正,李旭光,苏俏俏.科学与财富,2014(6):101~103.
[15]江平,蒋志城.浙江树人大学学报:自然科学版,2006,(2):37~40.
[16]A Verma,C K Phua,W Y Sim et al.Medicine,2016,95(26):e3996.
[17]张治青,廖梦尘,曾虹燕等.光谱学与光谱分析,2015,35(1):14~18.
[18]李冰,王奖,贾美林等.工业催化,2016,24(10):1~7.
[19]叶江涛,章琛,陈富强等.塑料工业,2018,(2):71~75.
[20]蔺道雷,田国峰,武德珍.中国塑料,2016,30(11):8~12.
[21]倪哲明,张连阳,夏盛杰等.稀有金属材料与工程,2016(s1):159~164.
[22]Q Kong,T Wu,J Wang et al.J.Nanosci.Nanotechnol.,2018,18(5):3660~3665.
[23]黄志义,武斌,康诚等.浙江大学学报(工学版),2016,50(1):27~32.
[24]陈艺兰,林琅,肖荔人等.中国塑料,2008(2):28~32.
[25]陈艺兰,肖良建,陈荣国等.中国塑料,2010,24(8):75~80.
[26]A A Bakr,G Eshaq,A M Rabie et al.Desalin.Water Treat.,2016,57(27):12632~12643.
[27]P H Chang,Y P Chang,Y H Lai et al.J.Alloys Compd.,2014,586:S498~S505.
[28]陈江超.中国科学院过程工程研究所硕士学位论文,2009.
[29]赵晓嫣.山东化工,2011,40(6):33~34.
[30]崔益顺.无机盐工业,2017,49(9):38~41.
[31]刘家伟,王容,李盈颖等.科技创新与应用,2017(16):19~20.
[32]戴昉纳,赵伟,由婷等.精细与专用化学品,2007,15(2):5~8.
[33]Y Y Ding,L Xu,G S Hu.Chin.Sci.Bull.,2011,56(35):3878~3883.
[34]Y X Yan,X Y Gu,L M Li et al.Fibers Polym.,2017,18(11):2060~2069.
[35]田雪梅.塑料助剂,2011,(6):13~15.
[36]童孟良,周芝兰,许沅沅.化工文摘,2008,(2):45~48.
[37]邵长生,沈钟,陈丽特等.塑料工业,1988,(6):40~43.
[38]尚松川,杨保俊,张睿辰等.复合材料学报,2017,34(8):1667~1673.
[39]S Majoni.J.Ther.Anal.Calorim.,2015,120(2):1435~1443.
[40]徐敏虹,潘国祥,陈海锋等.矿物学报,2017,37(4):395~400.
[41]S D Jiang,Z M Bai,G Tang et al.ACS Appl.Mater.Interf.,2014,6(16):14076~14086.
[42]林苗,郑利民.印染,2000,26(9):44~45.
[43]赵博,赵晓云,邹璐等.塑料助剂,2010,(3):6~8.
[44]张月琴,叶旭初.塑料科技,2007,35(9):110~113.
[45]冷尔唯,龚勋,张扬等.化工学报,2018,69(1):239~248.
[46]周卫平,吕秉玲.无机盐工业,1988,(3):16~18.
[47]L L Yu,F Lu,D C Qin et al.Wood Fiber Sci.,2017,49(2):125~133.
[48]李空.中国地质大学(北京)硕士学位论文,2016.
[49]G Varga,S Muráth,Bajcsi et al.React.Kinet.Mech.Cat.,2017,121(1):241~254.
[50]王娜,仲剑初,王洪志.无机盐工业,2016,48(1):25~27,48.
[51]贾修伟,刘治国.化工进展,2003,22(8):818~822.
[52]滕广远,陈俊宏.化工时刊,2018(4):28~32.
[53]郭文珊,勇雪.河南科技,2017(20):59~62.
[54]徐斌,余国民,刘海洋等.山东化工,2017,46(9):18~20.
[55]董珂.东北林业大学硕士学位论文,2016.
[56]但世辉,陈莉莉.化学教育,2012,33(3):71~72.
[57]宋真富.上海师范大学硕士学位论文,2015.
[58]M Shamsayei,Y Yamini,H Asiabi et al.Microchim.Acta,2018,185(3):192.
[59]L Li,W Gu,J Liu et al.Nano Res.,2015,8(2):682~694.
[60]Z Zhang,X Mei,C Xu et al.Sci.Chin.B,2005,48(2):107~114.
[61]Y Gao,Q Wang,J Wang et al.ACS Appl.Mater.Interf.,2014,6(7):5094~5104.
[62]X S Liu,X Y Gu,S Zhang et al.J.Appl.Polym.Sci.,2014,130(5):3645~3651.
[63]立青.中国人造板,2018,25(7):39.