北京地区中元古界下马岭组页岩地球化学特征及其地质意义
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摘要
对采自北京地区中元古界下马岭组的页岩样品,进行了地球化学研究,结果表明:主量元素Al2O3、Ca O和Na2O含量明显偏低,K2O和Mn O含量稍微偏低,Si O2、Ti O2及Fe2O3T含量同上地壳基本一致。微量元素及其比值特征显示源岩为混合源岩。稀土元素总量较高,轻稀土富集、重稀土平坦,铕明显负异常、铈弱负异常,各样品稀土元素配分模式与大陆上地壳一致,显示了沉积物具有同源性。源岩为来自于内蒙古隆起的花岗岩类、闪长岩类及基性岩的混合。微量元素比值及铈弱负异常的特征表明中元古界下马岭组页岩为覆水较深的还原环境沉积,源区构造背景为大陆岛弧。
Based on analyses of the sampled shales of field outcrops and well cuttings, the authors studied the geochemical characteristics of the shales of Mesoproterozoic Xiamaling Formation in Beijing. Al_2O_3, Na_2O and K_2O are depleted whereas SiO_2, TiO_2 and Fe_2O_3 Tare relatively enriched. The shales show homogeneous REE content,relatively enrichment of LREE and depletion of HREE,obvious negative Eu anomaly, and slightly negative Ce anomaly. The REE distribution patterns from different shale samples showing an affinity reveal that they have the same source rocks including granitic, dioritoid and mafic rocks from the upper continental crust of Inner Mongolia uplift, and the ratios of trace elements show these features too. They were deposited in a reducing environment with relatively deep water. The tectonic setting of the source area seems to have been a continental island arc.
Based on analyses of the sampled shales of field outcrops and well cuttings, the authors studied the geochemical characteristics of the shales of Mesoproterozoic Xiamaling Formation in Beijing. Al_2O_3, Na_2O and K_2O are depleted whereas SiO_2, TiO_2 and Fe_2O_3 Tare relatively enriched. The shales show homogeneous REE content,relatively enrichment of LREE and depletion of HREE,obvious negative Eu anomaly, and slightly negative Ce anomaly. The REE distribution patterns from different shale samples showing an affinity reveal that they have the same source rocks including granitic, dioritoid and mafic rocks from the upper continental crust of Inner Mongolia uplift, and the ratios of trace elements show these features too. They were deposited in a reducing environment with relatively deep water. The tectonic setting of the source area seems to have been a continental island arc.
引文
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Chen Jianfa and Sun Shengli.2004.Preliminary study of geochemical characteristics and formation of organic matter rich stratigraphy of Xiamaling Formation of later Proterozoic in north China[J].Natural Gas Geosciece,15(2):110~114(in Chinese).
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Fang Jie,Liu Baoquan,Jin Fengming,et al.2002.Source potential for generating hydrocarbon and exploration prospects of middle-upper Proterozoic in the Northern China[J].Acta Petrolei Sinica,23(4):18~24(in Chinese).
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Gao Linzhi,Ding Xiaozhong,Pang Weihua,et al.2011.New geologic time scale of Meso-and Neoproterozoic of China and geochronologic constraint by shrimp zircon U-Pb Dating[J].Journal of Stratigraphy,35:1~7(in Chinese with English abstract).
Gao Linzhi,Zhang Chuanheng,Shi Xiaoying,et al.2007.Zircon shrimp U-Pb dating of the Tuffbed in the Xiamaling Formation of the Qingbaikouan system in North China[J].Geological Bulletin of China,26:249~255(in Chinese with English abstract).
Graver J I and Scott T J.1995.Trace elements in shale as indicators of crustal provenance and terrainaccretion of the southern Canadiancordillera[J].Geol.Soc.Am.Bull.,107:440~453.
Hatch J R and Leventhal J S.1992.Relationship between inferred redox potential of the depositional environmental and geochemistry of the upper Pennsylvanian(Missourian)Stark Shale Member of the Dennis Limestope Wabaunsee County,Kansas,USA[J].Chemical Geology,99:65~82.
Li Huaikun,Lu Songnian,Li Huimin,et al.2009.Zircon and beddeleyite U-Pb precision dating of basicrock sills intruding Xiamaling Formation,North China[J].Geological Bulletin of China,28(10):1 396~1 404(in Chinese).
Li Junjian,Luo Zhenkuan,Yan Changhai,et al.2010.Structure framework and evolution of the North China Craton[J].Contributions to Geology and Mineral Resources Research,25(2):89~100(in Chinese).
Liu Qingjun,Ke Bailin,Lin Hailiang,et al.2014.Forming conditions and characteristics of shale gas in Mesoproterozoic Xiamaling Formation,Beijing[J].Geological Science and Technology Informaiton,33(2):92~97(in Chinese with English abstract).
Lu S N,Yang C L,Li H K,et al.2002.A group of rifting events in the terminal Paleoproterozoic in the North China Craton[J].Gondwana Research,5:123~131.
Mc Lennan S M.1989.Rare earth elements in sedimentary rocks:Influence of provenance and sedimentary processes[A].Lipin B R and Mc Kay G A.Geochemistry and Mineralogy of Rare Earth Elements[C].Mineralogical Society of America,Reviews in Mineralogy,21:169~200.
Mc Lennan S M,Hemming S,Mc Daniel D K,et al.1993.Geochemical approaches to sedimentation,provenance,and tectonics[A].Johnsson M J and Basu A.Processes Controlling the Composition of Clastic Sediments[C].Colorado:Geol.Soc.Am.Spec.,284:21~34.
Mclennan S M,Hemming S R,Taylor S R,et al.1995.Early proterozonic crustal evolution:geochemical and Nd-Pb isotopic evidence from metasedimentary rocks,southwestern North American[J].Geochimicaet Cosmo Chimica Acta,59:1 153~1 177.
Mclennan S M,Taylor S R and Hemming S R.2006.Composition,differentiation,and evolution of continental crust:constrains from sedimentary rocks and heat flow[A].Brown M and Rushmer T.Evolution and Differentiation of the Continental crust[C].92~134.
Pan Jianguo,Qu Yongqiang,Ma Rui,et al.2013.Sedimentary and tectonic evolution of the Meso-Neoproterozic strata in the Northern Margin of the North China block[J].Geological Journal of China University,19(1):109~122(in Chinese with English abstract).
Peng P,Zhai M G,Ernst R E,et al.2008.1A 1178 Galarge igneous province in the North China Craton:The Xiongper volcanic province and the North China Dyke Swarm[J].Lithos,1:260~280.
Pettijohn F J.1975.Sedimentary Rocks[M].3rd edition.Harper and Row Publishers,New York,1~628.
Qiao Xiufu and Gao Mai.1997.Carbonate Pb-Pb isotopic dating of Qingbaikou System in North China and its significa Ilce[J].Earth ScienceJournal of China University of Geosciences,22(1):1~7(in Chinese).
Shao L S,Tattergger K and Carbe Schoenberge C D.2001.Sandstone petrology and geochemistry of the Turpan Basin(NW China):implications for the tectonic evolution of a continental basin[J].Journal of Sedimentary Research,71(1):37~49.
Taylor S R and Mclennan S M.1985.The Continental Crust:Its composition and evolution[J].Blackwell Scientific Publications,Oxford,312.
Wang Jie and Chen Jianfa.2001.Depositional environment and source potential for generating hydrocarbon of Middle upper Proterozoic in the Northern China[J].Natural Gas Geoscience,12(3):27~33(in Chinese).
Wang Jie,Chen Jianfa and Dou Qilong.2004.Evaluation of the hydrocarbon generating potential for the possible hydrocarbon source rocks of the Middle upper Proterozoic in North Huabei area[J].Petroleum Geology&Experiment,26(2):206~211(in Chinese).
Wang Quan,Liu Xueya and Li Jintie.1991.Plate Tectonics Between Cathaysia and Angaraland in China[M].Peking University Press(in Chinese with English abstract).
Yang Xinglian,Zhu Maoyan,Zhao Yunlong,et al.2008.REE geochemical characteristics of the Ediacaran-lower Cambrian black rock series in Eastern Guizhou[J].Geological Review,54(1):3~15(in Chinese with English abstract).
Zhang Chen.2004.Hot-Tectonic events and evolution of north margin of the North China Craton in Meso-Neoproterozoic[J].Scientiarum Naturalium Universitatis Pekinensis,40(2):232~245(in Chinese with English abstract).
Zhao Yue,Chen Bin,Zhang Shuanhong,et al.2010.Pre-Yanshanian geological events in the northern margin of the North China Craton and its adjacent areas[J].37(4):900~915(in Chinese).
Zhou Hongrui,Mei Mingxiang,Luo Zhiqing,et al.2006.Sedimentary sequence and stratigraphic framework of the Neoproterozoic Qingbaikou system in the Yanshan region,North China[J].Earth Science Frontiers,13(6):280~290(in Chinese with English abstract).
Zhu Xiaoqing and Wang Zhonggang.1994.Geochemical characteristics of seiment at hot water region in the Okinawa Trough[A].Hu Ruizhong.Study on Geochemistry[C].Beijing:Seismological Press,108~112(in Chinese).
北京市地质矿产局.1991.北京市区域地质志[M].北京:地质出版社,1~598.
陈德潜,陈刚.1996.实用稀土元素地球化学[M].北京:冶金工业出版社,1~268.
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