不饱和聚酯树脂及其制品稳定化研究进展
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摘要
综述了近年来不饱和聚酯树及其制品稳定化方面的进展,包括在不饱和聚酯中添加抗老化助剂,及其在制品表面涂上防护层(胶衣树脂)。只使用单一的稳定剂效果不佳,必须将紫外线吸收剂,主抗氧剂、副抗氧剂和其他添加剂并用,才能取得较好的稳定效果。同时还介绍了改善玻璃纤维增强不饱和聚酯树脂耐水性能的方法。
We reviewed the recent advances in the stabilization of unsaturated polyester resins(UPRs)and its products, as well as coatings(gel coat resins) like glass fiber reinforced plastics(GFRP) and anti-aging additives and various stabilizers adopted, such as ultraviolet absorbents, hindered amine light stabilizers(HALS) and antioxidants. Compared with one single stabilizer, the combined use of ultraviolet absorbents, primary and auxiliary antioxidants and some other additives has the best effect on maintaining the stabilization of UPRs. Meanwhile, we also introduced how to adopt GFRP to strengthen the water resistance of UPRs.
We reviewed the recent advances in the stabilization of unsaturated polyester resins(UPRs)and its products, as well as coatings(gel coat resins) like glass fiber reinforced plastics(GFRP) and anti-aging additives and various stabilizers adopted, such as ultraviolet absorbents, hindered amine light stabilizers(HALS) and antioxidants. Compared with one single stabilizer, the combined use of ultraviolet absorbents, primary and auxiliary antioxidants and some other additives has the best effect on maintaining the stabilization of UPRs. Meanwhile, we also introduced how to adopt GFRP to strengthen the water resistance of UPRs.
引文
[1]黄发荣,郑安娜.不饱和聚酯树脂[M].北京:化学工业出版社,2001:149-150,79-82.
[2]Zveifel H,欧育湘,李建军.塑料添加剂手册(第3版)[M].北京:化学工业出版社,2005:252-253
[3]北京251厂.国外玻璃钢老化和防老化情况简介[J].玻璃钢/复合材料,1978,(1):19-23.
[4]汪冬生.室外暴露玻璃钢表面颜色耐久性的研究[J].广船科技,1996,(3):11-12.
[5]Huhband KE Russel J A.Photochemical Degradation of Glassy Polyester of Lowsoftening Point[J].Journal of Applied PolymerScience,1977,21:611-619.
[6]H P Abeysinghe.Degradation of Crosslinked Resins in Water and Electrolyte Solutions[J].Polymer,1982,23:1785-1789.
[7]Nakagawa Masateru.Weater-resistant and Transparent Unsaturated Polyester Composion and Their Molding:JP,293 847[P].2002-10-09.
[8]邹升.紫外线吸收剂UV-B的合成和应用[J].湖北化工,1999(2):23-24.
[9]Mu Shih Lin.Photostabilization of an Epoxy Resin by Forming Interpene-trating Polymer Networkswith Bisphenol-A Diacrylate[J].Polymer Deg-radation and Stability,1999,66(3):343-347.
[10]沃丁柱.透明玻璃钢的老化性能研究[J].玻璃钢/复合材料,1999,(1):22-25.
[11]刘雄亚,连福茂.组合稳定剂对透明聚醋玻璃钢防老化偶合效应[J].武汉工业大学学报,1988,(3):277-282
[12]Song Zhongjiang,Otto Vogl.Functional polymers 31ESCA Spectrosco-py of Polyesters Stabilized with Polymer Bound Ultraviolet Stabilizers[J].Polymer Bulletin,1984,12:245-251.
[13]张韦民,周菊兴.无色透明不饱和聚酯树脂的研究[J].工程塑料应用,1999,(7):8-10.
[14]周诗彪.玻璃钢表面耐侯性涂料层材料NPB-1的研究[J].常德师范学院学报(自然科学版),2000,(1):13-15.
[15]郑红琼,张雄军.玻璃钢制品的表面涂装技术[J].玻璃钢/复合材料,2002,(4):40-43.
[16]杨晓燕.玻璃钢表面的涂装[J].材料保护,1997,30(10):9-11.
[17]董永祺.国外胶衣研究新动向,建筑工业信息[J].1996(18):18
[18]汪泽霖,骨色胶衣的黄变现象[J],纤维复合材料,2006(3):8-13
[19]Hodeson Peter Clifford.UV-stable Thermosetting Polymer Coating Compostion Containing Unspolyesters and Vinylfunctionl Monomers and UV Stabilizers:WO,22752[P].2002-03-21
[20]Reynolds William.Ultra Violent Resistand Premix Compositions and Articles Using Such Composition:US.6337362[P].2002-01-08
[21]刘雄亚,熊传溪,刘立娟.透明玻璃钢表面防老化技术研究[J].纤维复合材料,2000,3(3):26-31
[22]曾念三,黄志雄,蔡绪福.耐水型胶衣树脂的合成[J].塑料工业,1988,(6):20-24
[23]王麒,朱超.船用不饱和聚酯树脂的耐水性研究[J].玻璃钢/复合材料,2010,(6):40-45
[24]刘卫红,赵林.环己醇封端不饱和聚酯树脂的合成及性能研究[J].精细石化化工进展,2007,8(5):49-55.
[25]吴雄.耐酸碱老化改性不饱和聚酯的合成及性能[J].热固性树脂,2013,28(6):1-5.
[26]常鹏.耐候性阻燃胶衣树脂的研究[J].新材料与新技术2016,42(4):48.
[2]Zveifel H,欧育湘,李建军.塑料添加剂手册(第3版)[M].北京:化学工业出版社,2005:252-253
[3]北京251厂.国外玻璃钢老化和防老化情况简介[J].玻璃钢/复合材料,1978,(1):19-23.
[4]汪冬生.室外暴露玻璃钢表面颜色耐久性的研究[J].广船科技,1996,(3):11-12.
[5]Huhband KE Russel J A.Photochemical Degradation of Glassy Polyester of Lowsoftening Point[J].Journal of Applied PolymerScience,1977,21:611-619.
[6]H P Abeysinghe.Degradation of Crosslinked Resins in Water and Electrolyte Solutions[J].Polymer,1982,23:1785-1789.
[7]Nakagawa Masateru.Weater-resistant and Transparent Unsaturated Polyester Composion and Their Molding:JP,293 847[P].2002-10-09.
[8]邹升.紫外线吸收剂UV-B的合成和应用[J].湖北化工,1999(2):23-24.
[9]Mu Shih Lin.Photostabilization of an Epoxy Resin by Forming Interpene-trating Polymer Networkswith Bisphenol-A Diacrylate[J].Polymer Deg-radation and Stability,1999,66(3):343-347.
[10]沃丁柱.透明玻璃钢的老化性能研究[J].玻璃钢/复合材料,1999,(1):22-25.
[11]刘雄亚,连福茂.组合稳定剂对透明聚醋玻璃钢防老化偶合效应[J].武汉工业大学学报,1988,(3):277-282
[12]Song Zhongjiang,Otto Vogl.Functional polymers 31ESCA Spectrosco-py of Polyesters Stabilized with Polymer Bound Ultraviolet Stabilizers[J].Polymer Bulletin,1984,12:245-251.
[13]张韦民,周菊兴.无色透明不饱和聚酯树脂的研究[J].工程塑料应用,1999,(7):8-10.
[14]周诗彪.玻璃钢表面耐侯性涂料层材料NPB-1的研究[J].常德师范学院学报(自然科学版),2000,(1):13-15.
[15]郑红琼,张雄军.玻璃钢制品的表面涂装技术[J].玻璃钢/复合材料,2002,(4):40-43.
[16]杨晓燕.玻璃钢表面的涂装[J].材料保护,1997,30(10):9-11.
[17]董永祺.国外胶衣研究新动向,建筑工业信息[J].1996(18):18
[18]汪泽霖,骨色胶衣的黄变现象[J],纤维复合材料,2006(3):8-13
[19]Hodeson Peter Clifford.UV-stable Thermosetting Polymer Coating Compostion Containing Unspolyesters and Vinylfunctionl Monomers and UV Stabilizers:WO,22752[P].2002-03-21
[20]Reynolds William.Ultra Violent Resistand Premix Compositions and Articles Using Such Composition:US.6337362[P].2002-01-08
[21]刘雄亚,熊传溪,刘立娟.透明玻璃钢表面防老化技术研究[J].纤维复合材料,2000,3(3):26-31
[22]曾念三,黄志雄,蔡绪福.耐水型胶衣树脂的合成[J].塑料工业,1988,(6):20-24
[23]王麒,朱超.船用不饱和聚酯树脂的耐水性研究[J].玻璃钢/复合材料,2010,(6):40-45
[24]刘卫红,赵林.环己醇封端不饱和聚酯树脂的合成及性能研究[J].精细石化化工进展,2007,8(5):49-55.
[25]吴雄.耐酸碱老化改性不饱和聚酯的合成及性能[J].热固性树脂,2013,28(6):1-5.
[26]常鹏.耐候性阻燃胶衣树脂的研究[J].新材料与新技术2016,42(4):48.