3D打印锂电池的研究现状及前景展望
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摘要
3D打印技术作为一种快速成型技术迅猛发展,并且正迅速改变着人们的生产生活方式。文章简要的说明了锂离子电池的发展需求和3D打印技术在该领域的优势,并且对3D打印电极材料以及国内外3D打印锂电池的发展现状进行了比较系统的介绍。最后,基于制备高能量密度和高功率密度的锂离子电池,分析了现今所存在的问题及发展方向,并对未来锂电池的制造与产业发展进行了前景展望。
As a rapid prototyping manufacturing,3 D printing technology has got sound momentum and is rapidly changing people's production and lifestyle. The development needs of lithium-ion batteries and the technical advantages of 3 D printing technology in this field were briefly described,and a systematic introduction was conducted to the development of 3 D printed electrode materials and 3 D printed lithium batteries at home and abroad.Finally,based on the preparation of lithium-ion batteries with high energy density and high power density,the existing problems and development directions were analyzed,and the future manufacturing and industrial development of lithium-ion batteries were prospected.
As a rapid prototyping manufacturing,3 D printing technology has got sound momentum and is rapidly changing people's production and lifestyle. The development needs of lithium-ion batteries and the technical advantages of 3 D printing technology in this field were briefly described,and a systematic introduction was conducted to the development of 3 D printed electrode materials and 3 D printed lithium batteries at home and abroad.Finally,based on the preparation of lithium-ion batteries with high energy density and high power density,the existing problems and development directions were analyzed,and the future manufacturing and industrial development of lithium-ion batteries were prospected.
引文
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[19]LEWIS J A. Direct ink writing of 3D functional materials[J]. Advanced Functional Materials,2010,16(17):2193-2204.
[20]JIANG Y,XU Z,HUANG T,et al.Direct 3D printing of ultralight graphene oxide aerogel microlattices[J].Advanced Functional Materials,2018,28(16):1707024.
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[22]AHN B Y,DUOSS E B,MOTALA M J,et al.Omnidirectional printing of flexible,stretchable,and spanning silver microelectrodes[J].Science,2009,323(5921):1590-1593
[23]AHN B Y,LORANG D J,DUOSS E B,et al.Direct-write assembly of microperiodic planar and spanning ITO microelectrodes[J].Chemical Communications,2010,46(38):7118-7120.
[24]SUN K,WEI T S,AHN B Y,et al.3D printing of interdigitated li-ion microbattery architectures[J].Advanced Materials,2013,25(33):4539-4543.
[25]HU J,JIANG Y,CUI S,et al. 3D printed cathodes of Li Mn1-xFexPO4nanocrystals achieve both ultrahighrate and high capacity for advanced lithium-ion battery[J]. Advanced Energy Materials,2016,6(18):1608-1656.
[26]王一博,赵九蓬. 3D打印低扭曲度超厚分级孔锂离子电池电极[J].现代化工,2017,37(12):118-122.
[27]THORAT I V,STEPHENSON D E,ZACHARIAS N A,et al.Quantifying tortuosity in porous Li-ion battery materials[J].Journal of Power Sources,2009,188(2):592-600.
[28]BAE C J,ERDONMEZ C K,HALLORAN J W,et al.Design of battery electrodes with dual-scale porosity to minimize tortuosity and maximize performance[J].Advanced Materials,2013,25(9):1254-1258.
[29]王一博,赵九蓬.3D打印柔性可穿戴锂离子电池[J].材料工程,2018,46(3):13-21.
[30]陈燎,唐兴伟,周涵,等.3D直写技术的研究进展与应用前景[J].中国科技论文在线,2015.
[31]李方方,张晓龙,吴怡,等.我国动力锂电池行业现状和发展趋势[J].交通节能与环保,2016,12(3):14-16.
[2]SCROSATI B,GARCHE J. Lithium batteries:status,prospects and future[J]. Journal of Power Sources,2010,195(9):2419-2430.
[3]王聪聪,詹仪.3D打印技术的应用与发展前景[J].印刷工程,2014(4):23-28.
[4]黄荣根.对3D打印技术的思考[J].科技创新与应用,2014,20:40-41.
[5]肖崇梁.用于三维锂离子电池的低温直写3D打印装备开发与工艺研究[D].深圳:深圳大学,2017.
[6]BINI M,MOZZATI M C,GALINETTO P,et al.Structural,spectroscopic and magnetic investigation of the Li Fe1-x MnxPO4,(x=0-0.18)solid solution[J].Journal of Solid State Chemistry,2009,182(7):1972-1981.
[7]CUI M,BAI P,JIANG Q,et al.A novel synthesis and characterization of Li FePO4,and Li FePO4/C as a cathode material for lithium-ion battery[J].Journal of Power Sources,2014,246(3):232-238.
[8]YANG K,DENG Z H,SUO J H.Synthesis and characterization of Li FePO4and Li FePO4/C cathode material from lithium carboxylic acid and Fe3+[J].Journal of Power Sources,2012,201(none):274-279.
[9]赵尧敏.喷墨打印锂离子薄膜电极和复合超电容材料的制备及电化学性能研究[D].上海:复旦大学,2006.
[10]FU K,WANG Y B,YAN C Y,et al.Graphene oxide-based electrode inks for 3D-Printed lithium-ion batteries[J].Advanced Materials,2016,28(13):2587-2594.
[11]佟泽汉.3D打印机在柔性锂离子电池极片制作中的应用[D].南京:南京邮电大学,2016.
[12]孙玉城.镍钴锰酸锂三元正极材料的研究与应用[J].无机盐工业,2014,46(1):1.
[13]左文婧,屈银虎,时晶晶,等.基于3D打印的锂离子电池正极墨水的制备[J].材料科学与工艺,2018:1-8.
[14]SMAY J E,GRATSON G M,SHEPHERD R F,et al.Directed colloidal assembly of 3D periodic structures[J].Advanced Materials,2010,14(18):1279-1283.
[15]JAKUS A E,SECOR E B,RUTZ A L,et al.Three-dimensional printing of high-content graphene scaffolds for electronic and biomedical applications[J].American Chemical Society Nano,2015,9(4):4636-4648.
[16]ESTHER G,BARG S,FRANCO J,et al. Printing in three dimensions with graphene[J]. Advanced Materials,2015,27(10):1688-1693.
[17]ZHU C,HAN Y J,DUOSS E B,et al.Highly compressible 3D periodic graphene aerogel microlattices[J].Nature Communications,2015,6:6962.
[18]ZHU C,LIU T,QIAN F,et al.Supercapacitors based on three-Dimensional hierarchical graphene aerogels with periodic macropores[J].Nano Letters,2016,16(6):3448-3456.
[19]LEWIS J A. Direct ink writing of 3D functional materials[J]. Advanced Functional Materials,2010,16(17):2193-2204.
[20]JIANG Y,XU Z,HUANG T,et al.Direct 3D printing of ultralight graphene oxide aerogel microlattices[J].Advanced Functional Materials,2018,28(16):1707024.
[21]TANG X,ZHOU H,CAI Z,et al.Generalized 3D printing of graphene-based mixed-dimensional hybrid aerogels[J].American Chemical Society Nano,2018,12(4).
[22]AHN B Y,DUOSS E B,MOTALA M J,et al.Omnidirectional printing of flexible,stretchable,and spanning silver microelectrodes[J].Science,2009,323(5921):1590-1593
[23]AHN B Y,LORANG D J,DUOSS E B,et al.Direct-write assembly of microperiodic planar and spanning ITO microelectrodes[J].Chemical Communications,2010,46(38):7118-7120.
[24]SUN K,WEI T S,AHN B Y,et al.3D printing of interdigitated li-ion microbattery architectures[J].Advanced Materials,2013,25(33):4539-4543.
[25]HU J,JIANG Y,CUI S,et al. 3D printed cathodes of Li Mn1-xFexPO4nanocrystals achieve both ultrahighrate and high capacity for advanced lithium-ion battery[J]. Advanced Energy Materials,2016,6(18):1608-1656.
[26]王一博,赵九蓬. 3D打印低扭曲度超厚分级孔锂离子电池电极[J].现代化工,2017,37(12):118-122.
[27]THORAT I V,STEPHENSON D E,ZACHARIAS N A,et al.Quantifying tortuosity in porous Li-ion battery materials[J].Journal of Power Sources,2009,188(2):592-600.
[28]BAE C J,ERDONMEZ C K,HALLORAN J W,et al.Design of battery electrodes with dual-scale porosity to minimize tortuosity and maximize performance[J].Advanced Materials,2013,25(9):1254-1258.
[29]王一博,赵九蓬.3D打印柔性可穿戴锂离子电池[J].材料工程,2018,46(3):13-21.
[30]陈燎,唐兴伟,周涵,等.3D直写技术的研究进展与应用前景[J].中国科技论文在线,2015.
[31]李方方,张晓龙,吴怡,等.我国动力锂电池行业现状和发展趋势[J].交通节能与环保,2016,12(3):14-16.