可控活性聚合多乙烯基单体制备新型单链超内环化聚合物的研究历史及进展
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摘要
多乙烯基单体因其方便易得、固有的反应多活性位点而一直是合成多种复杂拓扑结构聚合物的理想单体;然而Flory-Stockmayer(F-S)均相场理论及广泛的前期尝试已证实多乙烯基单体的聚合会在极低转化率(<10%)下形成凝胶,而无法进行可控聚合.近年来,可控活性聚合方法的发展为动力学控制下的多乙烯基单体聚合奠定了基础,并成功合成多种具有不同复杂结构的聚合物.特别地,合成了具有新颖拓扑结构的单链超内环化聚合物.本文综述了近年来多乙烯基单体聚合的历史,动力学控制下的可控活性聚合机理以及单链超内环化聚合物的聚合过程、结构特征、应用等,展望了该新颖结构聚合物的应用前景,并对多乙烯基单体的可控活性聚合领域的未来发展提出了建议.
Polymerization of multivinyl monomers(MVMs) can produce polymers with novel topological structure and different functionalities due to their inherent multiple reactive sites.However,the polymerization of MVMs would inevitably lead to a polymeric cross-linked network(gel) even at extremely low conversion rates(typically under 10%) according to the Flory-Stockmayer mean-field theory(F-S theory).Recently,the development of controlled/living radical polymerization(CRP) paved the way towards kinetically-controlled polymerization of MVMs allowing the synthesis of novel macromolecular architectures.In particular,a novel knotted polymeric structure was obtained.This review summarizes the kinetically-controlled mechanism of CRP as the recent,major development in the field of polymerization of MVMs.The synthesis methods,novel structures and applications of knotted/cyclized polymers are also included.Moreover,the prospects for the application of polymers with novel structures and the future development of CRP of MVMs are proposed.
Polymerization of multivinyl monomers(MVMs) can produce polymers with novel topological structure and different functionalities due to their inherent multiple reactive sites.However,the polymerization of MVMs would inevitably lead to a polymeric cross-linked network(gel) even at extremely low conversion rates(typically under 10%) according to the Flory-Stockmayer mean-field theory(F-S theory).Recently,the development of controlled/living radical polymerization(CRP) paved the way towards kinetically-controlled polymerization of MVMs allowing the synthesis of novel macromolecular architectures.In particular,a novel knotted polymeric structure was obtained.This review summarizes the kinetically-controlled mechanism of CRP as the recent,major development in the field of polymerization of MVMs.The synthesis methods,novel structures and applications of knotted/cyclized polymers are also included.Moreover,the prospects for the application of polymers with novel structures and the future development of CRP of MVMs are proposed.
引文
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44 Aied A,Zheng Y,Newland B,Wang WX.Biomacromolecules,2014,15:4520-4527
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2 Stockmayer WH.J Chem Phys,1944,12:125-131
3 Landin DT,Macosko CW.Macromolecules,1988,21:846-851
4 Dotson NA,Diekmann T,Macosko CW,Tirrell M.Macromolecules,1992,25:4490-4500
5 Qu QW,Liu GY,Lv XQ,Zhang BH,An ZS.ACS Macro Lett,2016,5:316-320
6 Zhao TY,Zheng Y,Poly J,Wang WX.Nat Commun,2013,4,doi:10.1038/ncomms2887
7 Flory PJ.Principles of Polymer Chemistry.New York:Cornell University Press,1953
8 Gao HF,Matyjaszewski K.Prog Polym Sci,2009,34:317-350
9 Flory PJ.J Chem Phys,1945,13:453-465
10 Walling C.J Am Chem Phys,1945,67:441-447
11 Matsumoto A.Adv Polym Sci,2007,123:41-80
12 Costello PA,Martin IK,Slark AT,Sherrington DC,Titterton A.Polymer,2002,43:245-254
13 O’Brien N,Mc Kee A,Sherrington DC,Slark AT,Titterton A.Polymer,2000,41:6027-6031
14 Baudry R,Sherrington DC.Macromolecules,2006,39:1455-1460
15 Sugiyama F,Satoh K,Kamigaito M.Macromolecules,2008,41:3042-3048
16 Xia JH,Zhang X,Matyjaszewski K.Macromolecules,1999,32:4482-4484
17 Gao HF,Matyjaszewski K.Macromolecules,2008,41:1118-1125
18 Gao HF,Miasnikova A,Matyjaszewski K.Macromolecules,2008,41:7843-7849
19 Ide N,Fukuda T.Macromolecules,1997,30:4268-4271
20 Ide N,Fukuda T.Macromolecules,1999,32:95-99
21 Liu BL,Kazlauciunas A,Guthrie JT,Perrier S.Macromolecules,2005,38:2131-2136
22 Bannister I,Billingham NC,Armes SP,Rannard SP,Findlay P.Macromolecules,2006,39:7483-7492
23 Rosselgong J,Armes SP,Barton W,Price D.Macromolecules,2009,42:5919-5924
24 Vo CD,Rosselgong J,Armes SP.Macromolecules,2007,40:7119-7125
25 Kurochkin SA,Grachev VP.Polym Sci Series C,2015,57:20-31
26 Yu Q,Zeng FQ,Zhu SP.Macromolecules,2001,34:1612-1618
27 Yu Q,Zhang JZ,Cheng ML,Zhu SP.Macromol Chem Phys,2006,207:287-294
28 Yu Q,Zhu YS,Ding YH,Zhu SP.Macromol Chem Phys,2008,209:551-556
29 Mori H,Tsukamoto M.Polymer,2011,52:635-645
30 Wang WX,Zheng Y,Roberts E,Duxbury CJ,Ding LF,Irvine DJ,Howdle SM.Macromolecules,2007,40:7184-7194
31 Zheng Y,Cao HL,Newland B,Dong YX,Pandit A,Wang WX.J Am Chem Soc,2011,133:13130-13137
32 Zhao TY,Zhang H,Zhou DZ,Gao YS,Dong YX,Greiser U,Tai HY,Wang WX.RSC Adv,2015,5:33823-33830
33 Zheng Y,Newland B,Tai HY,Pandit A,Wang WX.Chem Commun,2012,48:3085-3087
34 Gao YS,Zhou DZ,Zhao TY,Wei X,Mc Mahon S,Ahern JO,Wang W,Greiser U,Rodriguez BJ,Wang WX.Macromolecules,2015,48:6882-6889
35 Newland B,Zheng Y,Jin Y,Abu-Ru M,Cao HL,Wang WX,Pandit A.J Am Chem Soc,2012,134:4782-4789
36 Zhao TY,Zhang H,Newland B,Aied A,Zhou DZ,Wang WX.Angew Chem,2014,126:6209-6214
37 Newland B,Aied A,Pinoncely AV,Zheng Y,Zhao T,Zhang H,Niemeier R,Dowd E,Pandit A,Wang WX.Nanoscale,2014,6:7526-7533
38 Hanlon AM,Lyon CK,Berda EB.Macromolecules,2016,49:2-14
39 Mavila S,Eivgi O,Berkovich I,Lemcoff NG.Chem Rev,2016,116:878-961
40 Gonzalez-Burgos M,Latorre-Sanchez A,Pomposo JA.Chem Soc Rev,2015,44:6122-6142
41 Elliott JE,Bowman CN.Macromolecules,1999,32:8621-8628
42 Okay O,Kurz M,Lutz K,Funke W.Macromolecules,1995,28:2728-2737
43 Newland B,Abu-Rub M,Naughton M,Zheng Y,Pinoncely AV,Collin E,Dowd E,Wang WX,Pandit A.ACS Chem Neurosci,2013,4:540-546
44 Aied A,Zheng Y,Newland B,Wang WX.Biomacromolecules,2014,15:4520-4527
45 Cutlar L,Gao YS,Aied A,Greiser U,Murauer EM,Zhou DZ,Wang WX.Biomater Sci,2016,4:92-95