超高分子量聚乙烯催化聚合研究进展
|
摘要
超高分子量聚乙烯是一种线型结构的热塑性工程塑料,具有超强的抗冲击性、耐磨损性、耐化蚀性、抗黏附能力等优良的性能。综述了超高分子量聚乙烯的性能及聚合研究背景,重点介绍了用于超高分子量聚乙烯聚合的催化剂的发展,阐述了一种利用负载型催化剂制备解缠结超高分子量聚乙烯的方法,并对超高分子量聚乙烯催化聚合的发展方向进行了展望。
Ultra-high molecular weight polyethylene(UHMWPE) is a linear structural thermoplastic engineering plastic with excellent properties such as impact resistance,abrasion resistance,corrosion resistance and adhesion resistance. Advances in the research of catalytic polymerization of UHMWPE were reviewed. The properties and research background of UHMWPE were briefly summarized. Different kinds of catalysts for the catalytic polymerization of UHMWPE were discussed in detail. Furthermore,the synthesis method of a disentangled UHMWPE with supported catalyst was also introduced. The future research of the catalysts used for the synthesis of UHMWPE was prospected.
Ultra-high molecular weight polyethylene(UHMWPE) is a linear structural thermoplastic engineering plastic with excellent properties such as impact resistance,abrasion resistance,corrosion resistance and adhesion resistance. Advances in the research of catalytic polymerization of UHMWPE were reviewed. The properties and research background of UHMWPE were briefly summarized. Different kinds of catalysts for the catalytic polymerization of UHMWPE were discussed in detail. Furthermore,the synthesis method of a disentangled UHMWPE with supported catalyst was also introduced. The future research of the catalysts used for the synthesis of UHMWPE was prospected.
引文
[1]Kurtz S M.The UHMWPE Handbook:Ultra-high Molecular Weight Polyethylene in Total Joint Replacement[M].New York:Academic Press,2004:1-2.
[2]Carr D J.Failure mechanisms of yarns subjected to ballistic impact[J].J Mater Sci Lett,1999,18(7):585-588.
[3]Kelly J M.Ultra-high molecular weight polyethylene[J].JMacromol Sci,2002,42(3):355-371.
[4]Padmanabhan S,Sarma K R,Sharma S.Synthesis of ultrahigh molecular weight polyethylene using traditional heterogeneous Ziegler-Natta catalyst systems[J].Ind Eng Chem Res,2009,48(10):4866-4871.
[5]Roghieh J,Hossein Z G,Mohsen J,et al.Synthesizing UHMWPE using Ziegler-Natta catalyst system of MgCl2(ethoxide type)/TiCl4/tri-isobutylaluminum[J].Macromol Symp,2008,274(1):148-153.
[6]Mitsui Petrochemical Industries.Process for preparing ultrahigh-molecular-weight polyolefin fine powder:US4972035[P].1990-11-20.
[7]Nippon Oil Company.Process for preparing ultra-high molecular weight polyethylene:US4962167[P].1990-10-09.
[8]Zhang Hexin,Shin Y J,Lee D H,et al.Preparation of ultra high molecular weight polyethylene with MgCl2/TiCl4 catalyst:Effect of internal and external donor on molecular weight and molecular weight distribution[J].Polym Bull,2011,66(5):627-635.
[9]Thongdonjuit A,Trakarnpruk W,Strauss R H.Effect of electron donor on PE polymerization[J].J Met Mater Miner,2009,19:17-23.
[10]Martin R,Christian P.Controlling polyolefin properties by in-reactor blending,1-polymerization process,precise kinetics,and molecular properties of UHMW-PE polymers[J].Macromol React Eng,2012,6(8):302-317.
[11]Kouzai I,Liu Boping,Wada T,et al.Effects of hydrogen for different stereospecific active sites on ultra low TiCl3 loading supported catalyst[J].Macromol React Eng,2007,1(1):160-164.
[12]程军.通用塑料手册[M].北京:国防工业出版社,2007:119.
[13]张知先.合成树脂与塑料牌号手册(上册)[M].北京:化学工业出版社,2006:293.
[14]Andresen A,Cordes H G,Herwig J,et al.Halogen-free soluble Ziegler catalysts for ethylene polymerization.Control of molecular weight by the choice of the reaction temperature[J].Angew Chem,Int Ed,1977,88(20):689-690.
[15]Herwig J,Kaminsky W.Halogen-free soluble Ziegler catalysts with methylalumoxan as catalyst[J].Polym Bull,1983,9(8-9):464-469.
[16]Sinn H,Kaminsky W,Vollmer H J,et al.“Living polymers”on polymerization with extremely productive Ziegler catalysts[J].Angew Chem,Int Ed,1980,19(5):390-392.
[17]Alt H G,K?ppl A.Effect of the nature of metallocene complexes of GroupⅣmetals on their performance in catalytic ethylene and propylene polymerization[J].Chem Rev,2000,100(4):1205-1222.
[18]Kaminsky W.New polymers by metallocene catalysis[J].Macromol Chem Phys,1996,197(12):3907-3945.
[19]Ostoja Starzewski K A,Xin B S,Steinhauser N,et al.Donor-acceptor metallocene catalysts for the production of UHMW-PE:Pushing the selectivity for chain growth to its limits[J].Angew Chem,Int Ed,2006,45(11):1799-1803.
[20]Resconi L,Cavallo L,Fait A,et al.Selectivity in propene polymerization with metallocene catalysts[J].Chem Rev,2000,100(4):1253-1345.
[21]Resconi L,Chadwick J C,Cavallo L.Comprehensive OrganoMetallic ChemistryⅢ:From Fundamentals to Applications[M].New York:Elsevier Science,2007:1005.
[22]Jones R L,Armoush M.Catalysts for UHMWPE[J].Macromol Symp,2009,283/284(1):88-95.
[23]Corradini P,Guerra G,Cavallo L.Do new century catalysts unravel the mechanism of stereocontrol of old Ziegler-Natta catalysts?[J].Acc Chem Res,2004,37(4):231-241.
[24]Matsui S,Fujita T.FI catalysts:Super active new ethylene polymerization catalysts[J].Catal Today,2001,66(1):63-73.
[25]Yoshida Y,Matsui S,Takagi Y,et al.New titanium complexes having two pyrrolide-imine chelate ligands:Syntheses,structures,and ethylene polymerization behavior[J].Organometallics,2001,20(23):4793-4799.
[26]Edson J B,Wang Z,Kramer E J,et al.Fluorinated bis(phenoxyketimine)titanium complexes for the living,isoselective polymerization of propylene:Multiblock isotactic polypropylene copolymers via sequential monomer addition[J].J Am Chem Soc,2008,130(14):4968-4977.
[27]Makio H,Kashiwa N,Fujita T.FI catalysts:A new family of high performance catalysts for olefin polymerization[J].Adv Synth Catal,2002,344(5):477-493.
[28]Makio H,Fujita T.Development and application of FI catalysts for olefin polymerization:Unique catalysis and distinctive polymer formation[J].Acc Chem Res,2009,42(10):1532-1544.
[29]Makio H,Terao H,Iwashita A,et al.FI catalysts for olefin polymerization-A cornprehensive treatment[J].Chem Rev,2011,111(3):2363-2449.
[30]Weiser M S,Mülhaupt R.Living olefin polymerisation and block copolymer synthesis in the presence of a single-site catalyst containing a phenoxyimine ligand[J].Macromol Symp,2006,236:111-116.
[31]Elder M J,Okumura Y,Jones R L,et al.Synthesis and performance of ansa-metallocene catalysts with substituted heterocyclic and indenyl ligands[J].Kinet Catal,2006,47(2):192-197.
[32]Rastogi S,Lippits D,Talebi S,et al.Formation of entanglements in initially disentangled polymer melts[J].Macromolecules,2006,39(26):8882-8885.
[33]Romano D,Tops N,Andablo-Reyes E,et al.Influence of polymerization conditions on melting kinetics of low entangled UHMWPE and its implications on mechanical properties[J].Macromolecules,2014,47(14):4750-4760.
[34]Talebi S,Duchateau R,Rastogi S,et al.Molar mass and molecular weight distribution determination of UHMWPE synthesized using a living homogeneous catalyst[J].Macromolecules,2010,43(6):2780-2788.
[35]贺登峰,徐杰,关超,等.低缠结超高分子量聚乙烯的制备及其对线性低密度聚乙烯的增强作用[J].材料导报,2016,30(2):47-51,60.
[36]Rastogi S,Lippits D R,Peters G W M,et al.Heterogeneity in polymer melts from melting of polymer crystals[J].Nat Mater,2005,4(8):635-641.
[37]H?hne G W H,Rastogi S,Lippits D R.Melting kinetics in polymers[J].Phys Rev Lett,2006,96(21):218-303.
[38]Pandey A,Champouret Y,Rastogi S.Heterogeneity in the distribution of entanglement density during polymerization in disentangled ultrahigh molecular weight polyethylene[J].Macromolecules,2011,44(12):4952-4960.
[39]Ronca S,Forte G,Tjaden H,et al.Tailoring molecular structure via nanoparticles for solvent-free processing of ultra-high molecular weight polyethylene composites[J].Polymer,2012,53(14):2897-2907.
[40]Mitani M,Mohri J,Yoshida Y,et al.Living polymerization of ethylene catalyzed by titanium complexes having fluorinecontaining phenoxy-imine chelate ligands[J].J Am Chem Soc,2002,124(13):3327-3336.
[41]Gote R P,Mandal D,Patel K,et al.Judicious reduction of supported Ti catalyst enables access to disentangled ultrahigh molecular weight polyethylene[J].Macromolecules,2018,51(12):4541-4552.
[2]Carr D J.Failure mechanisms of yarns subjected to ballistic impact[J].J Mater Sci Lett,1999,18(7):585-588.
[3]Kelly J M.Ultra-high molecular weight polyethylene[J].JMacromol Sci,2002,42(3):355-371.
[4]Padmanabhan S,Sarma K R,Sharma S.Synthesis of ultrahigh molecular weight polyethylene using traditional heterogeneous Ziegler-Natta catalyst systems[J].Ind Eng Chem Res,2009,48(10):4866-4871.
[5]Roghieh J,Hossein Z G,Mohsen J,et al.Synthesizing UHMWPE using Ziegler-Natta catalyst system of MgCl2(ethoxide type)/TiCl4/tri-isobutylaluminum[J].Macromol Symp,2008,274(1):148-153.
[6]Mitsui Petrochemical Industries.Process for preparing ultrahigh-molecular-weight polyolefin fine powder:US4972035[P].1990-11-20.
[7]Nippon Oil Company.Process for preparing ultra-high molecular weight polyethylene:US4962167[P].1990-10-09.
[8]Zhang Hexin,Shin Y J,Lee D H,et al.Preparation of ultra high molecular weight polyethylene with MgCl2/TiCl4 catalyst:Effect of internal and external donor on molecular weight and molecular weight distribution[J].Polym Bull,2011,66(5):627-635.
[9]Thongdonjuit A,Trakarnpruk W,Strauss R H.Effect of electron donor on PE polymerization[J].J Met Mater Miner,2009,19:17-23.
[10]Martin R,Christian P.Controlling polyolefin properties by in-reactor blending,1-polymerization process,precise kinetics,and molecular properties of UHMW-PE polymers[J].Macromol React Eng,2012,6(8):302-317.
[11]Kouzai I,Liu Boping,Wada T,et al.Effects of hydrogen for different stereospecific active sites on ultra low TiCl3 loading supported catalyst[J].Macromol React Eng,2007,1(1):160-164.
[12]程军.通用塑料手册[M].北京:国防工业出版社,2007:119.
[13]张知先.合成树脂与塑料牌号手册(上册)[M].北京:化学工业出版社,2006:293.
[14]Andresen A,Cordes H G,Herwig J,et al.Halogen-free soluble Ziegler catalysts for ethylene polymerization.Control of molecular weight by the choice of the reaction temperature[J].Angew Chem,Int Ed,1977,88(20):689-690.
[15]Herwig J,Kaminsky W.Halogen-free soluble Ziegler catalysts with methylalumoxan as catalyst[J].Polym Bull,1983,9(8-9):464-469.
[16]Sinn H,Kaminsky W,Vollmer H J,et al.“Living polymers”on polymerization with extremely productive Ziegler catalysts[J].Angew Chem,Int Ed,1980,19(5):390-392.
[17]Alt H G,K?ppl A.Effect of the nature of metallocene complexes of GroupⅣmetals on their performance in catalytic ethylene and propylene polymerization[J].Chem Rev,2000,100(4):1205-1222.
[18]Kaminsky W.New polymers by metallocene catalysis[J].Macromol Chem Phys,1996,197(12):3907-3945.
[19]Ostoja Starzewski K A,Xin B S,Steinhauser N,et al.Donor-acceptor metallocene catalysts for the production of UHMW-PE:Pushing the selectivity for chain growth to its limits[J].Angew Chem,Int Ed,2006,45(11):1799-1803.
[20]Resconi L,Cavallo L,Fait A,et al.Selectivity in propene polymerization with metallocene catalysts[J].Chem Rev,2000,100(4):1253-1345.
[21]Resconi L,Chadwick J C,Cavallo L.Comprehensive OrganoMetallic ChemistryⅢ:From Fundamentals to Applications[M].New York:Elsevier Science,2007:1005.
[22]Jones R L,Armoush M.Catalysts for UHMWPE[J].Macromol Symp,2009,283/284(1):88-95.
[23]Corradini P,Guerra G,Cavallo L.Do new century catalysts unravel the mechanism of stereocontrol of old Ziegler-Natta catalysts?[J].Acc Chem Res,2004,37(4):231-241.
[24]Matsui S,Fujita T.FI catalysts:Super active new ethylene polymerization catalysts[J].Catal Today,2001,66(1):63-73.
[25]Yoshida Y,Matsui S,Takagi Y,et al.New titanium complexes having two pyrrolide-imine chelate ligands:Syntheses,structures,and ethylene polymerization behavior[J].Organometallics,2001,20(23):4793-4799.
[26]Edson J B,Wang Z,Kramer E J,et al.Fluorinated bis(phenoxyketimine)titanium complexes for the living,isoselective polymerization of propylene:Multiblock isotactic polypropylene copolymers via sequential monomer addition[J].J Am Chem Soc,2008,130(14):4968-4977.
[27]Makio H,Kashiwa N,Fujita T.FI catalysts:A new family of high performance catalysts for olefin polymerization[J].Adv Synth Catal,2002,344(5):477-493.
[28]Makio H,Fujita T.Development and application of FI catalysts for olefin polymerization:Unique catalysis and distinctive polymer formation[J].Acc Chem Res,2009,42(10):1532-1544.
[29]Makio H,Terao H,Iwashita A,et al.FI catalysts for olefin polymerization-A cornprehensive treatment[J].Chem Rev,2011,111(3):2363-2449.
[30]Weiser M S,Mülhaupt R.Living olefin polymerisation and block copolymer synthesis in the presence of a single-site catalyst containing a phenoxyimine ligand[J].Macromol Symp,2006,236:111-116.
[31]Elder M J,Okumura Y,Jones R L,et al.Synthesis and performance of ansa-metallocene catalysts with substituted heterocyclic and indenyl ligands[J].Kinet Catal,2006,47(2):192-197.
[32]Rastogi S,Lippits D,Talebi S,et al.Formation of entanglements in initially disentangled polymer melts[J].Macromolecules,2006,39(26):8882-8885.
[33]Romano D,Tops N,Andablo-Reyes E,et al.Influence of polymerization conditions on melting kinetics of low entangled UHMWPE and its implications on mechanical properties[J].Macromolecules,2014,47(14):4750-4760.
[34]Talebi S,Duchateau R,Rastogi S,et al.Molar mass and molecular weight distribution determination of UHMWPE synthesized using a living homogeneous catalyst[J].Macromolecules,2010,43(6):2780-2788.
[35]贺登峰,徐杰,关超,等.低缠结超高分子量聚乙烯的制备及其对线性低密度聚乙烯的增强作用[J].材料导报,2016,30(2):47-51,60.
[36]Rastogi S,Lippits D R,Peters G W M,et al.Heterogeneity in polymer melts from melting of polymer crystals[J].Nat Mater,2005,4(8):635-641.
[37]H?hne G W H,Rastogi S,Lippits D R.Melting kinetics in polymers[J].Phys Rev Lett,2006,96(21):218-303.
[38]Pandey A,Champouret Y,Rastogi S.Heterogeneity in the distribution of entanglement density during polymerization in disentangled ultrahigh molecular weight polyethylene[J].Macromolecules,2011,44(12):4952-4960.
[39]Ronca S,Forte G,Tjaden H,et al.Tailoring molecular structure via nanoparticles for solvent-free processing of ultra-high molecular weight polyethylene composites[J].Polymer,2012,53(14):2897-2907.
[40]Mitani M,Mohri J,Yoshida Y,et al.Living polymerization of ethylene catalyzed by titanium complexes having fluorinecontaining phenoxy-imine chelate ligands[J].J Am Chem Soc,2002,124(13):3327-3336.
[41]Gote R P,Mandal D,Patel K,et al.Judicious reduction of supported Ti catalyst enables access to disentangled ultrahigh molecular weight polyethylene[J].Macromolecules,2018,51(12):4541-4552.