含Fe或Sn的锆合金显微组织研究
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摘要
研究了含少量Fe或Sn的锆合金显微组织,结果表明Zr-Fe二元合金中的Fe元素(≤1.0%,质量分数),除极少量固溶外,基本上是以Zr_3Fe第二相的形式析出,而且随着Fe含量的增加,第二相种类不变,尺寸变大。Zr-Sn二元合金中添加的Sn(≤5.0%)是以完全固溶的状态存在于锆基体中,不会参与形成第二相粒子;添加Sn元素会阻碍Zr合金回复及再结晶进程。在Zr-Sn-Fe合金中,Sn元素的添加可以提高Fe在α-Zr中的固溶含量,并且通过阻碍Zr合金β相快冷时板条晶晶粒长大及Fe元素的迁移,影响Zr_3Fe第二相的尺度及分布,可以使其细化并分布更均匀。
The effect of Fe and/or Sn addition on the microstructure of Zr alloys was investigated. Results show that in Zr-Fe binary alloys(with Fe amount less than 1 wt%),very few amount of Fe element is dissolved in Zr alloys while most of the Fe is precipitated as Zr_3Fe phase. Moreover,the dimension of Zr_3Fe increases with the Fe content. However,the Sn element added(≤5.0 wt%) is entirely dissolved in Zr alloys,while no precipitate containing Sn element is found. The addition of the Sn element could hinder the recovery and recrystallization process of Zr alloys. In Zr-Sn-Fe ternary alloys,the addition of Sn element could increase the solubility of Fe in Zr alloys,and impede the grain growth of lath crystal and migration of Fe element during rapid cooling process of β-phase. Moreover,finer and more uniformly distributed Zr_3Fe phase are observed after addition of Sn element.
The effect of Fe and/or Sn addition on the microstructure of Zr alloys was investigated. Results show that in Zr-Fe binary alloys(with Fe amount less than 1 wt%),very few amount of Fe element is dissolved in Zr alloys while most of the Fe is precipitated as Zr_3Fe phase. Moreover,the dimension of Zr_3Fe increases with the Fe content. However,the Sn element added(≤5.0 wt%) is entirely dissolved in Zr alloys,while no precipitate containing Sn element is found. The addition of the Sn element could hinder the recovery and recrystallization process of Zr alloys. In Zr-Sn-Fe ternary alloys,the addition of Sn element could increase the solubility of Fe in Zr alloys,and impede the grain growth of lath crystal and migration of Fe element during rapid cooling process of β-phase. Moreover,finer and more uniformly distributed Zr_3Fe phase are observed after addition of Sn element.
引文
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[14]Yao Meiyi(姚美意),Zou Linghong(邹玲红),Xie Xingfei(谢兴飞)et al.Acta Metallurgica Sinica(金属学报)[J],2012,48:1097
[15]Dong Y,Motta A T,Marquis E A.Journal of Nuclear Materials[J],2013,442:270
[2]Yao Meiyi(姚美意),Li Shilu(李士炉),Zhang Xin(张欣)et al.Acta Metallurgica Sinica(金属学报)[J],2011,47(7):867
[3]Chen Heming(陈鹤鸣),Ma Chunlai(马春来),Bai Xinde(白新德).The Corrosion and Protection of Nuclear Materials(核反应堆材料腐蚀及其防护)[M].Beijing:Atomic Energy Press,1984:206
[4]Takeda K,Anada H.Zirconium in the Nuclear Industry:12th International Symposium[C].West Conshohocken,PA:ASTMInternational,2000:592
[5]Wei J,Frankel P,Polatidis E et al.Acta Materialia[J],2013,61:4200
[6]Wang J,Fan H,Xiong J et al.Nuclear Engineering and Design[J],2011,241:471
[7]Choudhuri G.,Jagannath,Kumar M K et al.Journal of Nuclear Materials[J],2013,441:178
[8]Yan Zhongbo(杨忠波),Zhao Wenjin(赵文金),Miao Zhi(苗志).Journal of Chinese Society for Corrosion and Protection(中国腐蚀与防护学报)[J],2013,33:117
[9]Nikulina A V,Markelov V A,Peregud M M.Zirconium in the Nuclear Industry:11th International Symposium[C].Germany:ASTM International,1996:785
[10]Bangaru N V.J Nucl Mater[J],1985,131:280
[11]Garzarolli F,Stehle H,Steinberg E.Zirconium in the Nuclear Industry,11th Symposium[C].West Consho-hocken:ASTMInternational,1996:12
[12]Ruhmann H,Manzel R,SELL H et al.Zirconium in the Nuclear Industry,11th Symposium[C].West Conshohocken:ASTM International,1996:865
[13]Chai Linjiang(柴林江),Luan Baifeng(栾佰峰),Zhou Yu(周宇)et al.The Chinese Journal of Nonferrous Metals(中国有色金属学报)[J],2012,22:1594
[14]Yao Meiyi(姚美意),Zou Linghong(邹玲红),Xie Xingfei(谢兴飞)et al.Acta Metallurgica Sinica(金属学报)[J],2012,48:1097
[15]Dong Y,Motta A T,Marquis E A.Journal of Nuclear Materials[J],2013,442:270